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4-Amino-2-hy­droxy­benzohydrazide

The asymmetric unit of the title compound, C(7)H(9)N(3)O(2), comprises two crystallographically independent mol­ecules (A and B). In each mol­ecule there is an intra­molecular O—H⋯O hydrogen bond making an S(6) ring motif. In the crystal, a pair of N—H⋯N hydrogen bonds link the two mol­ecules (A and...

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Detalles Bibliográficos
Autores principales: Kargar, Hadi, Kia, Reza, Tahir, Muhammad Nawaz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393929/
https://www.ncbi.nlm.nih.gov/pubmed/22798794
http://dx.doi.org/10.1107/S1600536812026190
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author Kargar, Hadi
Kia, Reza
Tahir, Muhammad Nawaz
author_facet Kargar, Hadi
Kia, Reza
Tahir, Muhammad Nawaz
author_sort Kargar, Hadi
collection PubMed
description The asymmetric unit of the title compound, C(7)H(9)N(3)O(2), comprises two crystallographically independent mol­ecules (A and B). In each mol­ecule there is an intra­molecular O—H⋯O hydrogen bond making an S(6) ring motif. In the crystal, a pair of N—H⋯N hydrogen bonds link the two mol­ecules (A and B) into a dimer with an R (2) (2)(6) ring motif. The B mol­ecules are linked via pairs of N—H⋯O hydrogen bonds, forming inversion dimers with an R (2) (2)(10) ring motif. The mol­ecules are further linked via other N—H⋯O hydrogen bonds, forming undulating two-dimensional networks lying parallel to the bc plane. These networks are finally linked via N—H⋯O hydrogen bonds, forming a three-dimensional structure.
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spelling pubmed-33939292012-07-13 4-Amino-2-hy­droxy­benzohydrazide Kargar, Hadi Kia, Reza Tahir, Muhammad Nawaz Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(7)H(9)N(3)O(2), comprises two crystallographically independent mol­ecules (A and B). In each mol­ecule there is an intra­molecular O—H⋯O hydrogen bond making an S(6) ring motif. In the crystal, a pair of N—H⋯N hydrogen bonds link the two mol­ecules (A and B) into a dimer with an R (2) (2)(6) ring motif. The B mol­ecules are linked via pairs of N—H⋯O hydrogen bonds, forming inversion dimers with an R (2) (2)(10) ring motif. The mol­ecules are further linked via other N—H⋯O hydrogen bonds, forming undulating two-dimensional networks lying parallel to the bc plane. These networks are finally linked via N—H⋯O hydrogen bonds, forming a three-dimensional structure. International Union of Crystallography 2012-06-16 /pmc/articles/PMC3393929/ /pubmed/22798794 http://dx.doi.org/10.1107/S1600536812026190 Text en © Kargar et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Kargar, Hadi
Kia, Reza
Tahir, Muhammad Nawaz
4-Amino-2-hy­droxy­benzohydrazide
title 4-Amino-2-hy­droxy­benzohydrazide
title_full 4-Amino-2-hy­droxy­benzohydrazide
title_fullStr 4-Amino-2-hy­droxy­benzohydrazide
title_full_unstemmed 4-Amino-2-hy­droxy­benzohydrazide
title_short 4-Amino-2-hy­droxy­benzohydrazide
title_sort 4-amino-2-hy­droxy­benzohydrazide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393929/
https://www.ncbi.nlm.nih.gov/pubmed/22798794
http://dx.doi.org/10.1107/S1600536812026190
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