N′-[(E)-3-Chloro-2-fluoro­benzyl­idene]-6-methyl­nicotinohydrazide monohydrate

The title compound, C(14)H(11)ClFN(3)O·H(2)O, exists in an E conformation with respect to the N=C bond. The pyridine ring forms a dihedral angle of 5.00 (9)° with the benzene ring. In the crystal, the ketone O atom accepts one O—H⋯O and one C—H⋯O hydrogen bond, the water O atom accepts one N—H⋯O and...

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Autores principales: Fun, Hoong-Kun, Quah, Ching Kheng, Shyma, P. C., Kalluraya, Balakrishna, Vidyashree, J. H. S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393933/
https://www.ncbi.nlm.nih.gov/pubmed/22798798
http://dx.doi.org/10.1107/S1600536812026736
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author Fun, Hoong-Kun
Quah, Ching Kheng
Shyma, P. C.
Kalluraya, Balakrishna
Vidyashree, J. H. S.
author_facet Fun, Hoong-Kun
Quah, Ching Kheng
Shyma, P. C.
Kalluraya, Balakrishna
Vidyashree, J. H. S.
author_sort Fun, Hoong-Kun
collection PubMed
description The title compound, C(14)H(11)ClFN(3)O·H(2)O, exists in an E conformation with respect to the N=C bond. The pyridine ring forms a dihedral angle of 5.00 (9)° with the benzene ring. In the crystal, the ketone O atom accepts one O—H⋯O and one C—H⋯O hydrogen bond, the water O atom accepts one N—H⋯O and two C—H⋯O hydrogen bonds and the pyridine N atom accepts one O—H⋯N hydrogen bond, forming layers parallel to the ab plane.
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spelling pubmed-33939332012-07-13 N′-[(E)-3-Chloro-2-fluoro­benzyl­idene]-6-methyl­nicotinohydrazide monohydrate Fun, Hoong-Kun Quah, Ching Kheng Shyma, P. C. Kalluraya, Balakrishna Vidyashree, J. H. S. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(14)H(11)ClFN(3)O·H(2)O, exists in an E conformation with respect to the N=C bond. The pyridine ring forms a dihedral angle of 5.00 (9)° with the benzene ring. In the crystal, the ketone O atom accepts one O—H⋯O and one C—H⋯O hydrogen bond, the water O atom accepts one N—H⋯O and two C—H⋯O hydrogen bonds and the pyridine N atom accepts one O—H⋯N hydrogen bond, forming layers parallel to the ab plane. International Union of Crystallography 2012-06-16 /pmc/articles/PMC3393933/ /pubmed/22798798 http://dx.doi.org/10.1107/S1600536812026736 Text en © Fun et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fun, Hoong-Kun
Quah, Ching Kheng
Shyma, P. C.
Kalluraya, Balakrishna
Vidyashree, J. H. S.
N′-[(E)-3-Chloro-2-fluoro­benzyl­idene]-6-methyl­nicotinohydrazide monohydrate
title N′-[(E)-3-Chloro-2-fluoro­benzyl­idene]-6-methyl­nicotinohydrazide monohydrate
title_full N′-[(E)-3-Chloro-2-fluoro­benzyl­idene]-6-methyl­nicotinohydrazide monohydrate
title_fullStr N′-[(E)-3-Chloro-2-fluoro­benzyl­idene]-6-methyl­nicotinohydrazide monohydrate
title_full_unstemmed N′-[(E)-3-Chloro-2-fluoro­benzyl­idene]-6-methyl­nicotinohydrazide monohydrate
title_short N′-[(E)-3-Chloro-2-fluoro­benzyl­idene]-6-methyl­nicotinohydrazide monohydrate
title_sort n′-[(e)-3-chloro-2-fluoro­benzyl­idene]-6-methyl­nicotinohydrazide monohydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393933/
https://www.ncbi.nlm.nih.gov/pubmed/22798798
http://dx.doi.org/10.1107/S1600536812026736
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