4,4′,6,6′-Tetra-tert-butyl-2,2′-[1,3-diazinane-1,3-diylbis(methyl­ene)]diphenol 0.25-hydrate

The title compound, C(34)H(54)N(2)O(2)·0.25H(2)O, the organic mol­ecule, a potential tetra­dentate ligand with a bulky phenolic donor, has overall mirror symmetry. A partially occupied water mol­ecule of solvation is present in the lattice. The six-membered 1,3-diazinane ring displays a chair confor...

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Detalles Bibliográficos
Autores principales: Zhang, Manman, Li, Li, Yuan, Fugen, Qian, Hui
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393934/
https://www.ncbi.nlm.nih.gov/pubmed/22798799
http://dx.doi.org/10.1107/S1600536812026505
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author Zhang, Manman
Li, Li
Yuan, Fugen
Qian, Hui
author_facet Zhang, Manman
Li, Li
Yuan, Fugen
Qian, Hui
author_sort Zhang, Manman
collection PubMed
description The title compound, C(34)H(54)N(2)O(2)·0.25H(2)O, the organic mol­ecule, a potential tetra­dentate ligand with a bulky phenolic donor, has overall mirror symmetry. A partially occupied water mol­ecule of solvation is present in the lattice. The six-membered 1,3-diazinane ring displays a chair conformation. An intra­molecular O—H⋯N hydrogen bond ocurs. In the crystal, mol­ecules are linked by O—H⋯O inter­actions.
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spelling pubmed-33939342012-07-13 4,4′,6,6′-Tetra-tert-butyl-2,2′-[1,3-diazinane-1,3-diylbis(methyl­ene)]diphenol 0.25-hydrate Zhang, Manman Li, Li Yuan, Fugen Qian, Hui Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(34)H(54)N(2)O(2)·0.25H(2)O, the organic mol­ecule, a potential tetra­dentate ligand with a bulky phenolic donor, has overall mirror symmetry. A partially occupied water mol­ecule of solvation is present in the lattice. The six-membered 1,3-diazinane ring displays a chair conformation. An intra­molecular O—H⋯N hydrogen bond ocurs. In the crystal, mol­ecules are linked by O—H⋯O inter­actions. International Union of Crystallography 2012-06-16 /pmc/articles/PMC3393934/ /pubmed/22798799 http://dx.doi.org/10.1107/S1600536812026505 Text en © Zhang et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Zhang, Manman
Li, Li
Yuan, Fugen
Qian, Hui
4,4′,6,6′-Tetra-tert-butyl-2,2′-[1,3-diazinane-1,3-diylbis(methyl­ene)]diphenol 0.25-hydrate
title 4,4′,6,6′-Tetra-tert-butyl-2,2′-[1,3-diazinane-1,3-diylbis(methyl­ene)]diphenol 0.25-hydrate
title_full 4,4′,6,6′-Tetra-tert-butyl-2,2′-[1,3-diazinane-1,3-diylbis(methyl­ene)]diphenol 0.25-hydrate
title_fullStr 4,4′,6,6′-Tetra-tert-butyl-2,2′-[1,3-diazinane-1,3-diylbis(methyl­ene)]diphenol 0.25-hydrate
title_full_unstemmed 4,4′,6,6′-Tetra-tert-butyl-2,2′-[1,3-diazinane-1,3-diylbis(methyl­ene)]diphenol 0.25-hydrate
title_short 4,4′,6,6′-Tetra-tert-butyl-2,2′-[1,3-diazinane-1,3-diylbis(methyl­ene)]diphenol 0.25-hydrate
title_sort 4,4′,6,6′-tetra-tert-butyl-2,2′-[1,3-diazinane-1,3-diylbis(methyl­ene)]diphenol 0.25-hydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393934/
https://www.ncbi.nlm.nih.gov/pubmed/22798799
http://dx.doi.org/10.1107/S1600536812026505
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