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4-{[(E)-2,3-Dihy­droxy­benzyl­idene]amino}-N-(5-methyl-1,2-oxazol-3-yl)benzene­sulfonamide

In the title compound, C(17)H(15)N(3)O(5)S, the 2,3-dihy­droxy­benzaldehyde unit is oriented at a dihedral angles of 16.83 (10) and 78.87 (6)° with the anilinic and 5-methyl-1,2-oxazol-3-amine groups, respectively. An S(6) loop exists due to intramolecular O—H⋯N hydrogen bonding. In the crystal, inv...

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Autores principales: Tahir, M. Nawaz, Khan, Abdul Haleem, Iqbal, Mohammad S., Munir, Christy, Aziz, Tariq
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393936/
https://www.ncbi.nlm.nih.gov/pubmed/22798801
http://dx.doi.org/10.1107/S1600536812026657
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author Tahir, M. Nawaz
Khan, Abdul Haleem
Iqbal, Mohammad S.
Munir, Christy
Aziz, Tariq
author_facet Tahir, M. Nawaz
Khan, Abdul Haleem
Iqbal, Mohammad S.
Munir, Christy
Aziz, Tariq
author_sort Tahir, M. Nawaz
collection PubMed
description In the title compound, C(17)H(15)N(3)O(5)S, the 2,3-dihy­droxy­benzaldehyde unit is oriented at a dihedral angles of 16.83 (10) and 78.87 (6)° with the anilinic and 5-methyl-1,2-oxazol-3-amine groups, respectively. An S(6) loop exists due to intramolecular O—H⋯N hydrogen bonding. In the crystal, inversion dimers with R (2) (2)(8) rings are formed due to N—H⋯N hydrogen bonding between the 5-methyl-1,2-oxazol-3-amine groups. These dimers are inter­linked by O—H⋯O hydrogen bonds, forming chains along [101] and resulting in R (2) (2)(26) rings. π–π inter­actions occur between the central benzene rings with a centroid–centroid distance of 3.7928 (16) Å.
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spelling pubmed-33939362012-07-13 4-{[(E)-2,3-Dihy­droxy­benzyl­idene]amino}-N-(5-methyl-1,2-oxazol-3-yl)benzene­sulfonamide Tahir, M. Nawaz Khan, Abdul Haleem Iqbal, Mohammad S. Munir, Christy Aziz, Tariq Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(17)H(15)N(3)O(5)S, the 2,3-dihy­droxy­benzaldehyde unit is oriented at a dihedral angles of 16.83 (10) and 78.87 (6)° with the anilinic and 5-methyl-1,2-oxazol-3-amine groups, respectively. An S(6) loop exists due to intramolecular O—H⋯N hydrogen bonding. In the crystal, inversion dimers with R (2) (2)(8) rings are formed due to N—H⋯N hydrogen bonding between the 5-methyl-1,2-oxazol-3-amine groups. These dimers are inter­linked by O—H⋯O hydrogen bonds, forming chains along [101] and resulting in R (2) (2)(26) rings. π–π inter­actions occur between the central benzene rings with a centroid–centroid distance of 3.7928 (16) Å. International Union of Crystallography 2012-06-16 /pmc/articles/PMC3393936/ /pubmed/22798801 http://dx.doi.org/10.1107/S1600536812026657 Text en © Tahir et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Tahir, M. Nawaz
Khan, Abdul Haleem
Iqbal, Mohammad S.
Munir, Christy
Aziz, Tariq
4-{[(E)-2,3-Dihy­droxy­benzyl­idene]amino}-N-(5-methyl-1,2-oxazol-3-yl)benzene­sulfonamide
title 4-{[(E)-2,3-Dihy­droxy­benzyl­idene]amino}-N-(5-methyl-1,2-oxazol-3-yl)benzene­sulfonamide
title_full 4-{[(E)-2,3-Dihy­droxy­benzyl­idene]amino}-N-(5-methyl-1,2-oxazol-3-yl)benzene­sulfonamide
title_fullStr 4-{[(E)-2,3-Dihy­droxy­benzyl­idene]amino}-N-(5-methyl-1,2-oxazol-3-yl)benzene­sulfonamide
title_full_unstemmed 4-{[(E)-2,3-Dihy­droxy­benzyl­idene]amino}-N-(5-methyl-1,2-oxazol-3-yl)benzene­sulfonamide
title_short 4-{[(E)-2,3-Dihy­droxy­benzyl­idene]amino}-N-(5-methyl-1,2-oxazol-3-yl)benzene­sulfonamide
title_sort 4-{[(e)-2,3-dihy­droxy­benzyl­idene]amino}-n-(5-methyl-1,2-oxazol-3-yl)benzene­sulfonamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393936/
https://www.ncbi.nlm.nih.gov/pubmed/22798801
http://dx.doi.org/10.1107/S1600536812026657
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