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4-{[(E)-2,3-Dihydroxybenzylidene]amino}-N-(5-methyl-1,2-oxazol-3-yl)benzenesulfonamide
In the title compound, C(17)H(15)N(3)O(5)S, the 2,3-dihydroxybenzaldehyde unit is oriented at a dihedral angles of 16.83 (10) and 78.87 (6)° with the anilinic and 5-methyl-1,2-oxazol-3-amine groups, respectively. An S(6) loop exists due to intramolecular O—H⋯N hydrogen bonding. In the crystal, inv...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393936/ https://www.ncbi.nlm.nih.gov/pubmed/22798801 http://dx.doi.org/10.1107/S1600536812026657 |
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author | Tahir, M. Nawaz Khan, Abdul Haleem Iqbal, Mohammad S. Munir, Christy Aziz, Tariq |
author_facet | Tahir, M. Nawaz Khan, Abdul Haleem Iqbal, Mohammad S. Munir, Christy Aziz, Tariq |
author_sort | Tahir, M. Nawaz |
collection | PubMed |
description | In the title compound, C(17)H(15)N(3)O(5)S, the 2,3-dihydroxybenzaldehyde unit is oriented at a dihedral angles of 16.83 (10) and 78.87 (6)° with the anilinic and 5-methyl-1,2-oxazol-3-amine groups, respectively. An S(6) loop exists due to intramolecular O—H⋯N hydrogen bonding. In the crystal, inversion dimers with R (2) (2)(8) rings are formed due to N—H⋯N hydrogen bonding between the 5-methyl-1,2-oxazol-3-amine groups. These dimers are interlinked by O—H⋯O hydrogen bonds, forming chains along [101] and resulting in R (2) (2)(26) rings. π–π interactions occur between the central benzene rings with a centroid–centroid distance of 3.7928 (16) Å. |
format | Online Article Text |
id | pubmed-3393936 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33939362012-07-13 4-{[(E)-2,3-Dihydroxybenzylidene]amino}-N-(5-methyl-1,2-oxazol-3-yl)benzenesulfonamide Tahir, M. Nawaz Khan, Abdul Haleem Iqbal, Mohammad S. Munir, Christy Aziz, Tariq Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(17)H(15)N(3)O(5)S, the 2,3-dihydroxybenzaldehyde unit is oriented at a dihedral angles of 16.83 (10) and 78.87 (6)° with the anilinic and 5-methyl-1,2-oxazol-3-amine groups, respectively. An S(6) loop exists due to intramolecular O—H⋯N hydrogen bonding. In the crystal, inversion dimers with R (2) (2)(8) rings are formed due to N—H⋯N hydrogen bonding between the 5-methyl-1,2-oxazol-3-amine groups. These dimers are interlinked by O—H⋯O hydrogen bonds, forming chains along [101] and resulting in R (2) (2)(26) rings. π–π interactions occur between the central benzene rings with a centroid–centroid distance of 3.7928 (16) Å. International Union of Crystallography 2012-06-16 /pmc/articles/PMC3393936/ /pubmed/22798801 http://dx.doi.org/10.1107/S1600536812026657 Text en © Tahir et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Tahir, M. Nawaz Khan, Abdul Haleem Iqbal, Mohammad S. Munir, Christy Aziz, Tariq 4-{[(E)-2,3-Dihydroxybenzylidene]amino}-N-(5-methyl-1,2-oxazol-3-yl)benzenesulfonamide |
title | 4-{[(E)-2,3-Dihydroxybenzylidene]amino}-N-(5-methyl-1,2-oxazol-3-yl)benzenesulfonamide |
title_full | 4-{[(E)-2,3-Dihydroxybenzylidene]amino}-N-(5-methyl-1,2-oxazol-3-yl)benzenesulfonamide |
title_fullStr | 4-{[(E)-2,3-Dihydroxybenzylidene]amino}-N-(5-methyl-1,2-oxazol-3-yl)benzenesulfonamide |
title_full_unstemmed | 4-{[(E)-2,3-Dihydroxybenzylidene]amino}-N-(5-methyl-1,2-oxazol-3-yl)benzenesulfonamide |
title_short | 4-{[(E)-2,3-Dihydroxybenzylidene]amino}-N-(5-methyl-1,2-oxazol-3-yl)benzenesulfonamide |
title_sort | 4-{[(e)-2,3-dihydroxybenzylidene]amino}-n-(5-methyl-1,2-oxazol-3-yl)benzenesulfonamide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393936/ https://www.ncbi.nlm.nih.gov/pubmed/22798801 http://dx.doi.org/10.1107/S1600536812026657 |
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