(Z)-3-(2-Meth­oxy­benz­yl)-1,5-benzo­thia­zepin-4(5H)-one

In the title compound, C(17)H(15)NO(2)S, the seven-membered thia­zepine ring adopts a distorted twist-boat conformation. The dihedral angle between the mean planes of the benzothia­zepin ring system and the attached benzene ring is 47.7 (1)°. In the crystal, pairs of N—H⋯O hydrogen bonds link invers...

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Detalles Bibliográficos
Autores principales: Selvakumar, R., Bakthadoss, M., Lakshmanan, D., Murugavel, S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393937/
https://www.ncbi.nlm.nih.gov/pubmed/22798802
http://dx.doi.org/10.1107/S160053681202661X
Descripción
Sumario:In the title compound, C(17)H(15)NO(2)S, the seven-membered thia­zepine ring adopts a distorted twist-boat conformation. The dihedral angle between the mean planes of the benzothia­zepin ring system and the attached benzene ring is 47.7 (1)°. In the crystal, pairs of N—H⋯O hydrogen bonds link inversion-related mol­ecules into dimers, generating R (2) (2)(8) ring motifs. These dimers are further connected into a chain along the a axis by C—H⋯O hydrogen bonds, resulting in R (2) (2)(14) ring motifs. The crystal packing also features C—H⋯π inter­actions.

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