(Z)-3-(2-Meth­oxy­benz­yl)-1,5-benzo­thia­zepin-4(5H)-one

In the title compound, C(17)H(15)NO(2)S, the seven-membered thia­zepine ring adopts a distorted twist-boat conformation. The dihedral angle between the mean planes of the benzothia­zepin ring system and the attached benzene ring is 47.7 (1)°. In the crystal, pairs of N—H⋯O hydrogen bonds link invers...

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Detalles Bibliográficos
Autores principales: Selvakumar, R., Bakthadoss, M., Lakshmanan, D., Murugavel, S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393937/
https://www.ncbi.nlm.nih.gov/pubmed/22798802
http://dx.doi.org/10.1107/S160053681202661X
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author Selvakumar, R.
Bakthadoss, M.
Lakshmanan, D.
Murugavel, S.
author_facet Selvakumar, R.
Bakthadoss, M.
Lakshmanan, D.
Murugavel, S.
author_sort Selvakumar, R.
collection PubMed
description In the title compound, C(17)H(15)NO(2)S, the seven-membered thia­zepine ring adopts a distorted twist-boat conformation. The dihedral angle between the mean planes of the benzothia­zepin ring system and the attached benzene ring is 47.7 (1)°. In the crystal, pairs of N—H⋯O hydrogen bonds link inversion-related mol­ecules into dimers, generating R (2) (2)(8) ring motifs. These dimers are further connected into a chain along the a axis by C—H⋯O hydrogen bonds, resulting in R (2) (2)(14) ring motifs. The crystal packing also features C—H⋯π inter­actions.
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spelling pubmed-33939372012-07-13 (Z)-3-(2-Meth­oxy­benz­yl)-1,5-benzo­thia­zepin-4(5H)-one Selvakumar, R. Bakthadoss, M. Lakshmanan, D. Murugavel, S. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(17)H(15)NO(2)S, the seven-membered thia­zepine ring adopts a distorted twist-boat conformation. The dihedral angle between the mean planes of the benzothia­zepin ring system and the attached benzene ring is 47.7 (1)°. In the crystal, pairs of N—H⋯O hydrogen bonds link inversion-related mol­ecules into dimers, generating R (2) (2)(8) ring motifs. These dimers are further connected into a chain along the a axis by C—H⋯O hydrogen bonds, resulting in R (2) (2)(14) ring motifs. The crystal packing also features C—H⋯π inter­actions. International Union of Crystallography 2012-06-16 /pmc/articles/PMC3393937/ /pubmed/22798802 http://dx.doi.org/10.1107/S160053681202661X Text en © Selvakumar et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Selvakumar, R.
Bakthadoss, M.
Lakshmanan, D.
Murugavel, S.
(Z)-3-(2-Meth­oxy­benz­yl)-1,5-benzo­thia­zepin-4(5H)-one
title (Z)-3-(2-Meth­oxy­benz­yl)-1,5-benzo­thia­zepin-4(5H)-one
title_full (Z)-3-(2-Meth­oxy­benz­yl)-1,5-benzo­thia­zepin-4(5H)-one
title_fullStr (Z)-3-(2-Meth­oxy­benz­yl)-1,5-benzo­thia­zepin-4(5H)-one
title_full_unstemmed (Z)-3-(2-Meth­oxy­benz­yl)-1,5-benzo­thia­zepin-4(5H)-one
title_short (Z)-3-(2-Meth­oxy­benz­yl)-1,5-benzo­thia­zepin-4(5H)-one
title_sort (z)-3-(2-meth­oxy­benz­yl)-1,5-benzo­thia­zepin-4(5h)-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393937/
https://www.ncbi.nlm.nih.gov/pubmed/22798802
http://dx.doi.org/10.1107/S160053681202661X
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AT murugavels z32methoxybenzyl15benzothiazepin45hone

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