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3-Acetyl-1-(4-methylphenyl)thiourea
The asymmetric unit of the title compound, C(10)H(12)N(2)OS, contains two independent molecules. In both molecules, the conformations of the two N—H bonds are anti to each other. Furthermore, the conformations of the amide C=S bonds and the C=O bonds are anti to each other. The dihedral angles bet...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393939/ https://www.ncbi.nlm.nih.gov/pubmed/22798804 http://dx.doi.org/10.1107/S1600536812026244 |
Sumario: | The asymmetric unit of the title compound, C(10)H(12)N(2)OS, contains two independent molecules. In both molecules, the conformations of the two N—H bonds are anti to each other. Furthermore, the conformations of the amide C=S bonds and the C=O bonds are anti to each other. The dihedral angles between the benzene ring and the side chain are 52.8 (1) and 68.0 (1)° in the two independent molecules. An intramolecular N—H⋯O hydrogen bond occurs in both independent molecules. In the crystal, molecules are linked into infinite chains along the a axis through a series of N—H⋯O and N—H⋯S hydrogen bonds. |
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