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3-Acetyl-1-(4-methyl­phen­yl)thio­urea

The asymmetric unit of the title compound, C(10)H(12)N(2)OS, contains two independent mol­ecules. In both mol­ecules, the conformations of the two N—H bonds are anti to each other. Furthermore, the conformations of the amide C=S bonds and the C=O bonds are anti to each other. The dihedral angles bet...

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Detalles Bibliográficos
Autores principales: Gowda, B. Thimme, Foro, Sabine, Kumar, Sharatha
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393939/
https://www.ncbi.nlm.nih.gov/pubmed/22798804
http://dx.doi.org/10.1107/S1600536812026244
Descripción
Sumario:The asymmetric unit of the title compound, C(10)H(12)N(2)OS, contains two independent mol­ecules. In both mol­ecules, the conformations of the two N—H bonds are anti to each other. Furthermore, the conformations of the amide C=S bonds and the C=O bonds are anti to each other. The dihedral angles between the benzene ring and the side chain are 52.8 (1) and 68.0 (1)° in the two independent mol­ecules. An intra­molecular N—H⋯O hydrogen bond occurs in both independent mol­ecules. In the crystal, mol­ecules are linked into infinite chains along the a axis through a series of N—H⋯O and N—H⋯S hydrogen bonds.