3-Acetyl-1-(4-methyl­phen­yl)thio­urea

The asymmetric unit of the title compound, C(10)H(12)N(2)OS, contains two independent mol­ecules. In both mol­ecules, the conformations of the two N—H bonds are anti to each other. Furthermore, the conformations of the amide C=S bonds and the C=O bonds are anti to each other. The dihedral angles bet...

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Detalles Bibliográficos
Autores principales: Gowda, B. Thimme, Foro, Sabine, Kumar, Sharatha
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393939/
https://www.ncbi.nlm.nih.gov/pubmed/22798804
http://dx.doi.org/10.1107/S1600536812026244
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author Gowda, B. Thimme
Foro, Sabine
Kumar, Sharatha
author_facet Gowda, B. Thimme
Foro, Sabine
Kumar, Sharatha
author_sort Gowda, B. Thimme
collection PubMed
description The asymmetric unit of the title compound, C(10)H(12)N(2)OS, contains two independent mol­ecules. In both mol­ecules, the conformations of the two N—H bonds are anti to each other. Furthermore, the conformations of the amide C=S bonds and the C=O bonds are anti to each other. The dihedral angles between the benzene ring and the side chain are 52.8 (1) and 68.0 (1)° in the two independent mol­ecules. An intra­molecular N—H⋯O hydrogen bond occurs in both independent mol­ecules. In the crystal, mol­ecules are linked into infinite chains along the a axis through a series of N—H⋯O and N—H⋯S hydrogen bonds.
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spelling pubmed-33939392012-07-13 3-Acetyl-1-(4-methyl­phen­yl)thio­urea Gowda, B. Thimme Foro, Sabine Kumar, Sharatha Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(10)H(12)N(2)OS, contains two independent mol­ecules. In both mol­ecules, the conformations of the two N—H bonds are anti to each other. Furthermore, the conformations of the amide C=S bonds and the C=O bonds are anti to each other. The dihedral angles between the benzene ring and the side chain are 52.8 (1) and 68.0 (1)° in the two independent mol­ecules. An intra­molecular N—H⋯O hydrogen bond occurs in both independent mol­ecules. In the crystal, mol­ecules are linked into infinite chains along the a axis through a series of N—H⋯O and N—H⋯S hydrogen bonds. International Union of Crystallography 2012-06-16 /pmc/articles/PMC3393939/ /pubmed/22798804 http://dx.doi.org/10.1107/S1600536812026244 Text en © Gowda et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Gowda, B. Thimme
Foro, Sabine
Kumar, Sharatha
3-Acetyl-1-(4-methyl­phen­yl)thio­urea
title 3-Acetyl-1-(4-methyl­phen­yl)thio­urea
title_full 3-Acetyl-1-(4-methyl­phen­yl)thio­urea
title_fullStr 3-Acetyl-1-(4-methyl­phen­yl)thio­urea
title_full_unstemmed 3-Acetyl-1-(4-methyl­phen­yl)thio­urea
title_short 3-Acetyl-1-(4-methyl­phen­yl)thio­urea
title_sort 3-acetyl-1-(4-methyl­phen­yl)thio­urea
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393939/
https://www.ncbi.nlm.nih.gov/pubmed/22798804
http://dx.doi.org/10.1107/S1600536812026244
work_keys_str_mv AT gowdabthimme 3acetyl14methylphenylthiourea
AT forosabine 3acetyl14methylphenylthiourea
AT kumarsharatha 3acetyl14methylphenylthiourea

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