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1′-Butyl-2-methyl-1′,2,2′,3,4,9-hexa­hydro­spiro­[benzo[f]isoindole-1,3′-indole]-2′,4,9-trione

In the title compound, C(24)H(22)N(2)O(3), the indoline and pyrrole-fused naphtho­quinone units are both essentially planar [r.m.s. deviations = 0.042 (3) and 0.133 (3) Å, respectively]. The pyrrole ring adopts a C-envelope conformation. The dihedral angle between the mean planes of the two five-mem...

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Detalles Bibliográficos
Autores principales: Jagadeesan, G., Sethusankar, K., Bhaskar, G., Perumal, P. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393950/
https://www.ncbi.nlm.nih.gov/pubmed/22798815
http://dx.doi.org/10.1107/S1600536812026748
Descripción
Sumario:In the title compound, C(24)H(22)N(2)O(3), the indoline and pyrrole-fused naphtho­quinone units are both essentially planar [r.m.s. deviations = 0.042 (3) and 0.133 (3) Å, respectively]. The pyrrole ring adopts a C-envelope conformation. The dihedral angle between the mean planes of the two five-membered rings is 89.94 (9)°. The O atoms deviate from the mean planes of the pyrrolidine and naphthalene rings by 0.0311 (2), 0.2570 (2) and 0.1669 (2) Å. In the crystal, C—H⋯O inter­actions generate dimers with R (2) (2)(16) and R (2) (2)(18) graph-set motifs. The carbonyl O atom is involved in bifurcated hydrogen bonding. C—H⋯π inter­actions also occur.