2-{(E)-[(3-Iodo-4-methyl­phen­yl)imino]­meth­yl}-4-(trifluoro­meth­oxy)phenol

The title compound, C(15)H(11)F(3)INO(2), adopts the enol–imine tautomeric form. The mol­ecule displays an E conformation with respect to the imine C=N double bond. The dihedral angle between the two benzene rings is 12.4 (2)°. The mol­ecular conformation is stabilized by an intra­molecular O—H⋯N hy...

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Detalles Bibliográficos
Autores principales: Pekdemir, Merve, Işık, Şamil, Alaman Ağar, Ayşen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393956/
https://www.ncbi.nlm.nih.gov/pubmed/22798821
http://dx.doi.org/10.1107/S1600536812026876
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author Pekdemir, Merve
Işık, Şamil
Alaman Ağar, Ayşen
author_facet Pekdemir, Merve
Işık, Şamil
Alaman Ağar, Ayşen
author_sort Pekdemir, Merve
collection PubMed
description The title compound, C(15)H(11)F(3)INO(2), adopts the enol–imine tautomeric form. The mol­ecule displays an E conformation with respect to the imine C=N double bond. The dihedral angle between the two benzene rings is 12.4 (2)°. The mol­ecular conformation is stabilized by an intra­molecular O—H⋯N hydrogen bond, which generates an S(6) ring motif. The trifluoro­meth­oxy­phenyl group is disordered over two sites with an occupancy ratio of 0.621 (6):0.379 (6). The crystal structure features C—H⋯π inter­actions.
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spelling pubmed-33939562012-07-13 2-{(E)-[(3-Iodo-4-methyl­phen­yl)imino]­meth­yl}-4-(trifluoro­meth­oxy)phenol Pekdemir, Merve Işık, Şamil Alaman Ağar, Ayşen Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(15)H(11)F(3)INO(2), adopts the enol–imine tautomeric form. The mol­ecule displays an E conformation with respect to the imine C=N double bond. The dihedral angle between the two benzene rings is 12.4 (2)°. The mol­ecular conformation is stabilized by an intra­molecular O—H⋯N hydrogen bond, which generates an S(6) ring motif. The trifluoro­meth­oxy­phenyl group is disordered over two sites with an occupancy ratio of 0.621 (6):0.379 (6). The crystal structure features C—H⋯π inter­actions. International Union of Crystallography 2012-06-20 /pmc/articles/PMC3393956/ /pubmed/22798821 http://dx.doi.org/10.1107/S1600536812026876 Text en © Pekdemir et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Pekdemir, Merve
Işık, Şamil
Alaman Ağar, Ayşen
2-{(E)-[(3-Iodo-4-methyl­phen­yl)imino]­meth­yl}-4-(trifluoro­meth­oxy)phenol
title 2-{(E)-[(3-Iodo-4-methyl­phen­yl)imino]­meth­yl}-4-(trifluoro­meth­oxy)phenol
title_full 2-{(E)-[(3-Iodo-4-methyl­phen­yl)imino]­meth­yl}-4-(trifluoro­meth­oxy)phenol
title_fullStr 2-{(E)-[(3-Iodo-4-methyl­phen­yl)imino]­meth­yl}-4-(trifluoro­meth­oxy)phenol
title_full_unstemmed 2-{(E)-[(3-Iodo-4-methyl­phen­yl)imino]­meth­yl}-4-(trifluoro­meth­oxy)phenol
title_short 2-{(E)-[(3-Iodo-4-methyl­phen­yl)imino]­meth­yl}-4-(trifluoro­meth­oxy)phenol
title_sort 2-{(e)-[(3-iodo-4-methyl­phen­yl)imino]­meth­yl}-4-(trifluoro­meth­oxy)phenol
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393956/
https://www.ncbi.nlm.nih.gov/pubmed/22798821
http://dx.doi.org/10.1107/S1600536812026876
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AT isıksamil 2e3iodo4methylphenyliminomethyl4trifluoromethoxyphenol
AT alamanagaraysen 2e3iodo4methylphenyliminomethyl4trifluoromethoxyphenol

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