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N-(4-Methylbenzyl)-3-nitroanilinium chloride
The cation of the title compound, C(14)H(15)N(2)O(2) (+)·Cl(−), comprises two almost ideally planar systems, 3-nitrophenyl (r.m.s. deviation = 0.0117 Å) and 4-methylphenyl (r.m.s. deviation = 0.238 Å), separated by the central C—N bond, and with their mean planes inclined to one another by 61.36 (...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393960/ https://www.ncbi.nlm.nih.gov/pubmed/22798825 http://dx.doi.org/10.1107/S1600536812026281 |
Sumario: | The cation of the title compound, C(14)H(15)N(2)O(2) (+)·Cl(−), comprises two almost ideally planar systems, 3-nitrophenyl (r.m.s. deviation = 0.0117 Å) and 4-methylphenyl (r.m.s. deviation = 0.238 Å), separated by the central C—N bond, and with their mean planes inclined to one another by 61.36 (5)°. In the crystal, hydrogen-bonded chains running along [001] are generated by connecting neighbouring molecules via N—H⋯Cl hydrogen bonds and consolidated by C—H⋯Cl and C—H⋯O interactions. Within these chains, fused R (2) (1)(6) and R (3) (2)(10) ring motifs are formed. Parallel chains are further linked into a two-dimensional network parallel to (100) via C—H⋯O interactions. |
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