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3,3′-Di-n-propyl-1,1′-(1,3-phenylenedimethylene)di(1H-imidazol-3-ium) bis(hexafluorophosphate)
In the title compound, C(20)H(28)N(4) (2+)·2PF(6) (−), the dihedral angles between the benzene ring and the imidazole rings are 70.18 (11) and 69.83 (11)°, while the imidazole rings form a dihedral angle of 40.52 (12)°. In the crystal, weak C—H⋯F interactions link the molecules into a two-dimensio...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393961/ https://www.ncbi.nlm.nih.gov/pubmed/22798826 http://dx.doi.org/10.1107/S1600536812026955 |
| _version_ | 1782237791619383296 |
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| author | Haque, Rosenani A. Nasri, S. Fatimah Rosli, Mohd Mustaqim Fun, Hoong-Kun |
| author_facet | Haque, Rosenani A. Nasri, S. Fatimah Rosli, Mohd Mustaqim Fun, Hoong-Kun |
| author_sort | Haque, Rosenani A. |
| collection | PubMed |
| description | In the title compound, C(20)H(28)N(4) (2+)·2PF(6) (−), the dihedral angles between the benzene ring and the imidazole rings are 70.18 (11) and 69.83 (11)°, while the imidazole rings form a dihedral angle of 40.52 (12)°. In the crystal, weak C—H⋯F interactions link the molecules into a two-dimensional network parallel to (001). A π–π interaction with a centroid–centroid distance of 3.601 (1) Å is also observed in the crystal structure. |
| format | Online Article Text |
| id | pubmed-3393961 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-33939612012-07-13 3,3′-Di-n-propyl-1,1′-(1,3-phenylenedimethylene)di(1H-imidazol-3-ium) bis(hexafluorophosphate) Haque, Rosenani A. Nasri, S. Fatimah Rosli, Mohd Mustaqim Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(20)H(28)N(4) (2+)·2PF(6) (−), the dihedral angles between the benzene ring and the imidazole rings are 70.18 (11) and 69.83 (11)°, while the imidazole rings form a dihedral angle of 40.52 (12)°. In the crystal, weak C—H⋯F interactions link the molecules into a two-dimensional network parallel to (001). A π–π interaction with a centroid–centroid distance of 3.601 (1) Å is also observed in the crystal structure. International Union of Crystallography 2012-06-20 /pmc/articles/PMC3393961/ /pubmed/22798826 http://dx.doi.org/10.1107/S1600536812026955 Text en © Haque et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Organic Papers Haque, Rosenani A. Nasri, S. Fatimah Rosli, Mohd Mustaqim Fun, Hoong-Kun 3,3′-Di-n-propyl-1,1′-(1,3-phenylenedimethylene)di(1H-imidazol-3-ium) bis(hexafluorophosphate) |
| title | 3,3′-Di-n-propyl-1,1′-(1,3-phenylenedimethylene)di(1H-imidazol-3-ium) bis(hexafluorophosphate) |
| title_full | 3,3′-Di-n-propyl-1,1′-(1,3-phenylenedimethylene)di(1H-imidazol-3-ium) bis(hexafluorophosphate) |
| title_fullStr | 3,3′-Di-n-propyl-1,1′-(1,3-phenylenedimethylene)di(1H-imidazol-3-ium) bis(hexafluorophosphate) |
| title_full_unstemmed | 3,3′-Di-n-propyl-1,1′-(1,3-phenylenedimethylene)di(1H-imidazol-3-ium) bis(hexafluorophosphate) |
| title_short | 3,3′-Di-n-propyl-1,1′-(1,3-phenylenedimethylene)di(1H-imidazol-3-ium) bis(hexafluorophosphate) |
| title_sort | 3,3′-di-n-propyl-1,1′-(1,3-phenylenedimethylene)di(1h-imidazol-3-ium) bis(hexafluorophosphate) |
| topic | Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393961/ https://www.ncbi.nlm.nih.gov/pubmed/22798826 http://dx.doi.org/10.1107/S1600536812026955 |
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