3-Methyl-4-[2-(4-nitro­phen­yl)hydrazin-1-yl­idene]-5-oxo-4,5-dihydro-1H-pyrazole-1-carbothio­amide

The asymmetric unit of the title compound, C(11)H(10)N(6)O(3)S, contains two independent mol­ecules, each of which is stabilized by an intra­molecular N—H⋯O hydrogen bond, forming an S(6) ring motif. In one mol­ecule, the pyrazole ring forms a dihedral angle of 10.93 (14)° with the benzene ring. The...

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Autores principales: Fun, Hoong-Kun, Quah, Ching Kheng, Shetty, Shobhitha, Kalluraya, Balakrishna, Babu, M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393969/
https://www.ncbi.nlm.nih.gov/pubmed/22798834
http://dx.doi.org/10.1107/S1600536812027134
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author Fun, Hoong-Kun
Quah, Ching Kheng
Shetty, Shobhitha
Kalluraya, Balakrishna
Babu, M.
author_facet Fun, Hoong-Kun
Quah, Ching Kheng
Shetty, Shobhitha
Kalluraya, Balakrishna
Babu, M.
author_sort Fun, Hoong-Kun
collection PubMed
description The asymmetric unit of the title compound, C(11)H(10)N(6)O(3)S, contains two independent mol­ecules, each of which is stabilized by an intra­molecular N—H⋯O hydrogen bond, forming an S(6) ring motif. In one mol­ecule, the pyrazole ring forms a dihedral angle of 10.93 (14)° with the benzene ring. The corresponding dihedral angle in the other mol­ecule is 7.03 (14)°. In the crystal, mol­ecules are linked via pairs of (N,N)—H⋯O bifurcated acceptor bonds which, together with C—H⋯O hydrogen bonds, form sheets parallel to (001).
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spelling pubmed-33939692012-07-13 3-Methyl-4-[2-(4-nitro­phen­yl)hydrazin-1-yl­idene]-5-oxo-4,5-dihydro-1H-pyrazole-1-carbothio­amide Fun, Hoong-Kun Quah, Ching Kheng Shetty, Shobhitha Kalluraya, Balakrishna Babu, M. Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(11)H(10)N(6)O(3)S, contains two independent mol­ecules, each of which is stabilized by an intra­molecular N—H⋯O hydrogen bond, forming an S(6) ring motif. In one mol­ecule, the pyrazole ring forms a dihedral angle of 10.93 (14)° with the benzene ring. The corresponding dihedral angle in the other mol­ecule is 7.03 (14)°. In the crystal, mol­ecules are linked via pairs of (N,N)—H⋯O bifurcated acceptor bonds which, together with C—H⋯O hydrogen bonds, form sheets parallel to (001). International Union of Crystallography 2012-06-23 /pmc/articles/PMC3393969/ /pubmed/22798834 http://dx.doi.org/10.1107/S1600536812027134 Text en © Fun et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fun, Hoong-Kun
Quah, Ching Kheng
Shetty, Shobhitha
Kalluraya, Balakrishna
Babu, M.
3-Methyl-4-[2-(4-nitro­phen­yl)hydrazin-1-yl­idene]-5-oxo-4,5-dihydro-1H-pyrazole-1-carbothio­amide
title 3-Methyl-4-[2-(4-nitro­phen­yl)hydrazin-1-yl­idene]-5-oxo-4,5-dihydro-1H-pyrazole-1-carbothio­amide
title_full 3-Methyl-4-[2-(4-nitro­phen­yl)hydrazin-1-yl­idene]-5-oxo-4,5-dihydro-1H-pyrazole-1-carbothio­amide
title_fullStr 3-Methyl-4-[2-(4-nitro­phen­yl)hydrazin-1-yl­idene]-5-oxo-4,5-dihydro-1H-pyrazole-1-carbothio­amide
title_full_unstemmed 3-Methyl-4-[2-(4-nitro­phen­yl)hydrazin-1-yl­idene]-5-oxo-4,5-dihydro-1H-pyrazole-1-carbothio­amide
title_short 3-Methyl-4-[2-(4-nitro­phen­yl)hydrazin-1-yl­idene]-5-oxo-4,5-dihydro-1H-pyrazole-1-carbothio­amide
title_sort 3-methyl-4-[2-(4-nitro­phen­yl)hydrazin-1-yl­idene]-5-oxo-4,5-dihydro-1h-pyrazole-1-carbothio­amide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393969/
https://www.ncbi.nlm.nih.gov/pubmed/22798834
http://dx.doi.org/10.1107/S1600536812027134
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