5-Methyl-1-[(4-methyl­phen­yl)sulfon­yl]-1H-pyrazol-3-yl 4-methyl­benzene­sulfonate

In the title compound, C(18)H(18)N(2)O(5)S(2), the tolyl rings are oriented at a dihedral angle of 16.15 (11)° with respect to one another. The 5-methyl-1H-pyrazol-3-ol ring is roughly planar (r.m.s. deviation = 0.0231 Å) and subtends angles of 73.82 (8) and 89.85 (8)° with the tolyl rings. In the c...

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Autores principales: Murtaza, Shahzad, Kausar, Naghmana, Tahir, M. Nawaz, Tariq, Javaria, Bibi, Samaira
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393995/
https://www.ncbi.nlm.nih.gov/pubmed/22798860
http://dx.doi.org/10.1107/S1600536812027717
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author Murtaza, Shahzad
Kausar, Naghmana
Tahir, M. Nawaz
Tariq, Javaria
Bibi, Samaira
author_facet Murtaza, Shahzad
Kausar, Naghmana
Tahir, M. Nawaz
Tariq, Javaria
Bibi, Samaira
author_sort Murtaza, Shahzad
collection PubMed
description In the title compound, C(18)H(18)N(2)O(5)S(2), the tolyl rings are oriented at a dihedral angle of 16.15 (11)° with respect to one another. The 5-methyl-1H-pyrazol-3-ol ring is roughly planar (r.m.s. deviation = 0.0231 Å) and subtends angles of 73.82 (8) and 89.85 (8)° with the tolyl rings. In the crystal, very weak π–π inter­actions between tolyl groups, with centroid–centroid distances of 4.1364 (19) and 4.0630 (16) Å, together with a C—H⋯π contact generate a three-dimensional network.
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spelling pubmed-33939952012-07-13 5-Methyl-1-[(4-methyl­phen­yl)sulfon­yl]-1H-pyrazol-3-yl 4-methyl­benzene­sulfonate Murtaza, Shahzad Kausar, Naghmana Tahir, M. Nawaz Tariq, Javaria Bibi, Samaira Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(18)H(18)N(2)O(5)S(2), the tolyl rings are oriented at a dihedral angle of 16.15 (11)° with respect to one another. The 5-methyl-1H-pyrazol-3-ol ring is roughly planar (r.m.s. deviation = 0.0231 Å) and subtends angles of 73.82 (8) and 89.85 (8)° with the tolyl rings. In the crystal, very weak π–π inter­actions between tolyl groups, with centroid–centroid distances of 4.1364 (19) and 4.0630 (16) Å, together with a C—H⋯π contact generate a three-dimensional network. International Union of Crystallography 2012-06-23 /pmc/articles/PMC3393995/ /pubmed/22798860 http://dx.doi.org/10.1107/S1600536812027717 Text en © Murtaza et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Murtaza, Shahzad
Kausar, Naghmana
Tahir, M. Nawaz
Tariq, Javaria
Bibi, Samaira
5-Methyl-1-[(4-methyl­phen­yl)sulfon­yl]-1H-pyrazol-3-yl 4-methyl­benzene­sulfonate
title 5-Methyl-1-[(4-methyl­phen­yl)sulfon­yl]-1H-pyrazol-3-yl 4-methyl­benzene­sulfonate
title_full 5-Methyl-1-[(4-methyl­phen­yl)sulfon­yl]-1H-pyrazol-3-yl 4-methyl­benzene­sulfonate
title_fullStr 5-Methyl-1-[(4-methyl­phen­yl)sulfon­yl]-1H-pyrazol-3-yl 4-methyl­benzene­sulfonate
title_full_unstemmed 5-Methyl-1-[(4-methyl­phen­yl)sulfon­yl]-1H-pyrazol-3-yl 4-methyl­benzene­sulfonate
title_short 5-Methyl-1-[(4-methyl­phen­yl)sulfon­yl]-1H-pyrazol-3-yl 4-methyl­benzene­sulfonate
title_sort 5-methyl-1-[(4-methyl­phen­yl)sulfon­yl]-1h-pyrazol-3-yl 4-methyl­benzene­sulfonate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393995/
https://www.ncbi.nlm.nih.gov/pubmed/22798860
http://dx.doi.org/10.1107/S1600536812027717
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AT tahirmnawaz 5methyl14methylphenylsulfonyl1hpyrazol3yl4methylbenzenesulfonate
AT tariqjavaria 5methyl14methylphenylsulfonyl1hpyrazol3yl4methylbenzenesulfonate
AT bibisamaira 5methyl14methylphenylsulfonyl1hpyrazol3yl4methylbenzenesulfonate

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