Phenazin-5-ium bromide

In the title compound, C(12)H(9)N(2) (+)·Br(−), the protonated tricyclic ring system is slightly twisted, with a dihedral angle of 3.9 (1)° between the two outer benzene rings. In the crystal, N—H⋯Br and C—H⋯Br hydrogen bonds link two cations and two bromide anions into centrosymmetric assemblies, w...

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Detalles Bibliográficos
Autores principales: Zhang, Gong-Xiao, Li, Ping, Dong, Jian, Chen, Hong-Yu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3394001/
https://www.ncbi.nlm.nih.gov/pubmed/22798866
http://dx.doi.org/10.1107/S1600536812027869
Descripción
Sumario:In the title compound, C(12)H(9)N(2) (+)·Br(−), the protonated tricyclic ring system is slightly twisted, with a dihedral angle of 3.9 (1)° between the two outer benzene rings. In the crystal, N—H⋯Br and C—H⋯Br hydrogen bonds link two cations and two bromide anions into centrosymmetric assemblies, which are further packed into stacks along [010] via π–π inter­actions between the aromatic rings [centroid–centroid distance = 3.725 (4) Å].

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