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Phenazin-5-ium bromide
In the title compound, C(12)H(9)N(2) (+)·Br(−), the protonated tricyclic ring system is slightly twisted, with a dihedral angle of 3.9 (1)° between the two outer benzene rings. In the crystal, N—H⋯Br and C—H⋯Br hydrogen bonds link two cations and two bromide anions into centrosymmetric assemblies, w...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3394001/ https://www.ncbi.nlm.nih.gov/pubmed/22798866 http://dx.doi.org/10.1107/S1600536812027869 |
| _version_ | 1782237800700051456 |
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| author | Zhang, Gong-Xiao Li, Ping Dong, Jian Chen, Hong-Yu |
| author_facet | Zhang, Gong-Xiao Li, Ping Dong, Jian Chen, Hong-Yu |
| author_sort | Zhang, Gong-Xiao |
| collection | PubMed |
| description | In the title compound, C(12)H(9)N(2) (+)·Br(−), the protonated tricyclic ring system is slightly twisted, with a dihedral angle of 3.9 (1)° between the two outer benzene rings. In the crystal, N—H⋯Br and C—H⋯Br hydrogen bonds link two cations and two bromide anions into centrosymmetric assemblies, which are further packed into stacks along [010] via π–π interactions between the aromatic rings [centroid–centroid distance = 3.725 (4) Å]. |
| format | Online Article Text |
| id | pubmed-3394001 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-33940012012-07-13 Phenazin-5-ium bromide Zhang, Gong-Xiao Li, Ping Dong, Jian Chen, Hong-Yu Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(12)H(9)N(2) (+)·Br(−), the protonated tricyclic ring system is slightly twisted, with a dihedral angle of 3.9 (1)° between the two outer benzene rings. In the crystal, N—H⋯Br and C—H⋯Br hydrogen bonds link two cations and two bromide anions into centrosymmetric assemblies, which are further packed into stacks along [010] via π–π interactions between the aromatic rings [centroid–centroid distance = 3.725 (4) Å]. International Union of Crystallography 2012-06-23 /pmc/articles/PMC3394001/ /pubmed/22798866 http://dx.doi.org/10.1107/S1600536812027869 Text en © Zhang et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Organic Papers Zhang, Gong-Xiao Li, Ping Dong, Jian Chen, Hong-Yu Phenazin-5-ium bromide |
| title | Phenazin-5-ium bromide |
| title_full | Phenazin-5-ium bromide |
| title_fullStr | Phenazin-5-ium bromide |
| title_full_unstemmed | Phenazin-5-ium bromide |
| title_short | Phenazin-5-ium bromide |
| title_sort | phenazin-5-ium bromide |
| topic | Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3394001/ https://www.ncbi.nlm.nih.gov/pubmed/22798866 http://dx.doi.org/10.1107/S1600536812027869 |
| work_keys_str_mv | AT zhanggongxiao phenazin5iumbromide AT liping phenazin5iumbromide AT dongjian phenazin5iumbromide AT chenhongyu phenazin5iumbromide |