(Z)-3′,6′-Bis(diethyl­amino)-2-(4-oxopent-2-en-2-yl­amino)­spiro­[isoindoline-1,9′-xanthen]-3-one

In the title compound, C(33)H(38)N(4)O(3), the mean planes of the 9H-xanthene unit and spiro­lactam (nine-atom) core are almost mutually perpendicular at 87.26 (6)°. Intra­molecular N—H⋯O and C—H⋯N inter­actions influence the 4-oxo­pent-2-en-2-yl­amino conformation. In the crystal, weak C—H⋯O hydrog...

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Detalles Bibliográficos
Autores principales: Guo, Chang-Bin, He, Ri-Cai, Li, Ai-Min
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3394002/
https://www.ncbi.nlm.nih.gov/pubmed/22798867
http://dx.doi.org/10.1107/S1600536812027602
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author Guo, Chang-Bin
He, Ri-Cai
Li, Ai-Min
author_facet Guo, Chang-Bin
He, Ri-Cai
Li, Ai-Min
author_sort Guo, Chang-Bin
collection PubMed
description In the title compound, C(33)H(38)N(4)O(3), the mean planes of the 9H-xanthene unit and spiro­lactam (nine-atom) core are almost mutually perpendicular at 87.26 (6)°. Intra­molecular N—H⋯O and C—H⋯N inter­actions influence the 4-oxo­pent-2-en-2-yl­amino conformation. In the crystal, weak C—H⋯O hydrogen bonds link the mol­ecules into chains along [001].
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spelling pubmed-33940022012-07-13 (Z)-3′,6′-Bis(diethyl­amino)-2-(4-oxopent-2-en-2-yl­amino)­spiro­[isoindoline-1,9′-xanthen]-3-one Guo, Chang-Bin He, Ri-Cai Li, Ai-Min Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(33)H(38)N(4)O(3), the mean planes of the 9H-xanthene unit and spiro­lactam (nine-atom) core are almost mutually perpendicular at 87.26 (6)°. Intra­molecular N—H⋯O and C—H⋯N inter­actions influence the 4-oxo­pent-2-en-2-yl­amino conformation. In the crystal, weak C—H⋯O hydrogen bonds link the mol­ecules into chains along [001]. International Union of Crystallography 2012-06-27 /pmc/articles/PMC3394002/ /pubmed/22798867 http://dx.doi.org/10.1107/S1600536812027602 Text en © Guo et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Guo, Chang-Bin
He, Ri-Cai
Li, Ai-Min
(Z)-3′,6′-Bis(diethyl­amino)-2-(4-oxopent-2-en-2-yl­amino)­spiro­[isoindoline-1,9′-xanthen]-3-one
title (Z)-3′,6′-Bis(diethyl­amino)-2-(4-oxopent-2-en-2-yl­amino)­spiro­[isoindoline-1,9′-xanthen]-3-one
title_full (Z)-3′,6′-Bis(diethyl­amino)-2-(4-oxopent-2-en-2-yl­amino)­spiro­[isoindoline-1,9′-xanthen]-3-one
title_fullStr (Z)-3′,6′-Bis(diethyl­amino)-2-(4-oxopent-2-en-2-yl­amino)­spiro­[isoindoline-1,9′-xanthen]-3-one
title_full_unstemmed (Z)-3′,6′-Bis(diethyl­amino)-2-(4-oxopent-2-en-2-yl­amino)­spiro­[isoindoline-1,9′-xanthen]-3-one
title_short (Z)-3′,6′-Bis(diethyl­amino)-2-(4-oxopent-2-en-2-yl­amino)­spiro­[isoindoline-1,9′-xanthen]-3-one
title_sort (z)-3′,6′-bis(diethyl­amino)-2-(4-oxopent-2-en-2-yl­amino)­spiro­[isoindoline-1,9′-xanthen]-3-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3394002/
https://www.ncbi.nlm.nih.gov/pubmed/22798867
http://dx.doi.org/10.1107/S1600536812027602
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