Bicyclo­[2.2.1]hept-2-en-7-yl 4-bromo­benzoate

The structure of the title compound, C(14)H(13)BrO(2), which contains a norbornenyl group and a 4-bromo­benzoate ester at the single C-atom bridge, has been redetermined [see McDonald & Trotter (1965 ▶). Acta Cryst. 19, 456–463] to modern standards to establish high-precision geometrical data to...

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Detalles Bibliográficos
Autores principales: Lloyd, Barry A., Arif, Atta M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3394005/
https://www.ncbi.nlm.nih.gov/pubmed/22798870
http://dx.doi.org/10.1107/S1600536812027882
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author Lloyd, Barry A.
Arif, Atta M.
author_facet Lloyd, Barry A.
Arif, Atta M.
author_sort Lloyd, Barry A.
collection PubMed
description The structure of the title compound, C(14)H(13)BrO(2), which contains a norbornenyl group and a 4-bromo­benzoate ester at the single C-atom bridge, has been redetermined [see McDonald & Trotter (1965 ▶). Acta Cryst. 19, 456–463] to modern standards to establish high-precision geometrical data to compare with norbornyl and other tetra­cyclic 4-bromo­benzoates. Possible structural evidence is sought to help explain solvolytic reactivities.
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spelling pubmed-33940052012-07-13 Bicyclo­[2.2.1]hept-2-en-7-yl 4-bromo­benzoate Lloyd, Barry A. Arif, Atta M. Acta Crystallogr Sect E Struct Rep Online Organic Papers The structure of the title compound, C(14)H(13)BrO(2), which contains a norbornenyl group and a 4-bromo­benzoate ester at the single C-atom bridge, has been redetermined [see McDonald & Trotter (1965 ▶). Acta Cryst. 19, 456–463] to modern standards to establish high-precision geometrical data to compare with norbornyl and other tetra­cyclic 4-bromo­benzoates. Possible structural evidence is sought to help explain solvolytic reactivities. International Union of Crystallography 2012-06-27 /pmc/articles/PMC3394005/ /pubmed/22798870 http://dx.doi.org/10.1107/S1600536812027882 Text en © Lloyd and Arif 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Lloyd, Barry A.
Arif, Atta M.
Bicyclo­[2.2.1]hept-2-en-7-yl 4-bromo­benzoate
title Bicyclo­[2.2.1]hept-2-en-7-yl 4-bromo­benzoate
title_full Bicyclo­[2.2.1]hept-2-en-7-yl 4-bromo­benzoate
title_fullStr Bicyclo­[2.2.1]hept-2-en-7-yl 4-bromo­benzoate
title_full_unstemmed Bicyclo­[2.2.1]hept-2-en-7-yl 4-bromo­benzoate
title_short Bicyclo­[2.2.1]hept-2-en-7-yl 4-bromo­benzoate
title_sort bicyclo­[2.2.1]hept-2-en-7-yl 4-bromo­benzoate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3394005/
https://www.ncbi.nlm.nih.gov/pubmed/22798870
http://dx.doi.org/10.1107/S1600536812027882
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