c-5-Hy­droxy-r-2,c-4-bis­(meth­oxy­carbon­yl)-t-5-methyl-t-3-(3-nitro­phen­yl)cyclo­hexa­none

In the title compound, C(17)H(19)NO(8) [systematic name = dimethyl 4-hydroxy-4-methyl-2-(3-nitrophenyl)-6-oxocyclohexane-1,3-dicarboxylate], the cyclo­hexa­none ring exhibits a chair conformation. The meth­oxy­carbonyl groups are oriented in opposite directions with respect to the cyclo­hexa­none ri...

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Autores principales: Rizwana Begum, S., Hema, R., Pandiarajan, K., Balasubramanian, Sridhar, Anitha, A.G.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3394008/
https://www.ncbi.nlm.nih.gov/pubmed/22798873
http://dx.doi.org/10.1107/S1600536812027377
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author Rizwana Begum, S.
Hema, R.
Pandiarajan, K.
Balasubramanian, Sridhar
Anitha, A.G.
author_facet Rizwana Begum, S.
Hema, R.
Pandiarajan, K.
Balasubramanian, Sridhar
Anitha, A.G.
author_sort Rizwana Begum, S.
collection PubMed
description In the title compound, C(17)H(19)NO(8) [systematic name = dimethyl 4-hydroxy-4-methyl-2-(3-nitrophenyl)-6-oxocyclohexane-1,3-dicarboxylate], the cyclo­hexa­none ring exhibits a chair conformation. The meth­oxy­carbonyl groups are oriented in opposite directions with respect to the cyclo­hexa­none ring. In the crystal, O—H⋯O hydrogen bonds links the mol­ecules into chains running parallel to the a axis. These chains are connected by weak C—H⋯O hydrogen bonds, forming sheets parallel to the ab plane.
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spelling pubmed-33940082012-07-13 c-5-Hy­droxy-r-2,c-4-bis­(meth­oxy­carbon­yl)-t-5-methyl-t-3-(3-nitro­phen­yl)cyclo­hexa­none Rizwana Begum, S. Hema, R. Pandiarajan, K. Balasubramanian, Sridhar Anitha, A.G. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(17)H(19)NO(8) [systematic name = dimethyl 4-hydroxy-4-methyl-2-(3-nitrophenyl)-6-oxocyclohexane-1,3-dicarboxylate], the cyclo­hexa­none ring exhibits a chair conformation. The meth­oxy­carbonyl groups are oriented in opposite directions with respect to the cyclo­hexa­none ring. In the crystal, O—H⋯O hydrogen bonds links the mol­ecules into chains running parallel to the a axis. These chains are connected by weak C—H⋯O hydrogen bonds, forming sheets parallel to the ab plane. International Union of Crystallography 2012-06-27 /pmc/articles/PMC3394008/ /pubmed/22798873 http://dx.doi.org/10.1107/S1600536812027377 Text en © Rizwana Begum et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Rizwana Begum, S.
Hema, R.
Pandiarajan, K.
Balasubramanian, Sridhar
Anitha, A.G.
c-5-Hy­droxy-r-2,c-4-bis­(meth­oxy­carbon­yl)-t-5-methyl-t-3-(3-nitro­phen­yl)cyclo­hexa­none
title c-5-Hy­droxy-r-2,c-4-bis­(meth­oxy­carbon­yl)-t-5-methyl-t-3-(3-nitro­phen­yl)cyclo­hexa­none
title_full c-5-Hy­droxy-r-2,c-4-bis­(meth­oxy­carbon­yl)-t-5-methyl-t-3-(3-nitro­phen­yl)cyclo­hexa­none
title_fullStr c-5-Hy­droxy-r-2,c-4-bis­(meth­oxy­carbon­yl)-t-5-methyl-t-3-(3-nitro­phen­yl)cyclo­hexa­none
title_full_unstemmed c-5-Hy­droxy-r-2,c-4-bis­(meth­oxy­carbon­yl)-t-5-methyl-t-3-(3-nitro­phen­yl)cyclo­hexa­none
title_short c-5-Hy­droxy-r-2,c-4-bis­(meth­oxy­carbon­yl)-t-5-methyl-t-3-(3-nitro­phen­yl)cyclo­hexa­none
title_sort c-5-hy­droxy-r-2,c-4-bis­(meth­oxy­carbon­yl)-t-5-methyl-t-3-(3-nitro­phen­yl)cyclo­hexa­none
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3394008/
https://www.ncbi.nlm.nih.gov/pubmed/22798873
http://dx.doi.org/10.1107/S1600536812027377
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