10-(6-Hy­droxy­hexa-2,4-diyn-1-yl)-10H-phenothia­zine 5-oxide

The title compound, C(18)H(13)NO(2)S, has two independent mol­ecules (A and B) with similar conformations in the asymmetric unit. Both phenothia­zine moieties have a butterfly structure [dihedral angles between benzene rings = 155.17 (7) and 161.71 (7)°, respectively], and the central six-membered r...

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Detalles Bibliográficos
Autores principales: Tabata, Hideyuki, Okuno, Tsunehisa
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3394009/
https://www.ncbi.nlm.nih.gov/pubmed/22798874
http://dx.doi.org/10.1107/S1600536812027511
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author Tabata, Hideyuki
Okuno, Tsunehisa
author_facet Tabata, Hideyuki
Okuno, Tsunehisa
author_sort Tabata, Hideyuki
collection PubMed
description The title compound, C(18)H(13)NO(2)S, has two independent mol­ecules (A and B) with similar conformations in the asymmetric unit. Both phenothia­zine moieties have a butterfly structure [dihedral angles between benzene rings = 155.17 (7) and 161.71 (7)°, respectively], and the central six-membered rings have a boat form. In the crystal, the A and B mol­ecules stack alternately along the b axis. The A and B mol­ecules are linked by O—H⋯O=S hydrogen bonds, forming zigzag chains along [10-1].
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spelling pubmed-33940092012-07-13 10-(6-Hy­droxy­hexa-2,4-diyn-1-yl)-10H-phenothia­zine 5-oxide Tabata, Hideyuki Okuno, Tsunehisa Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(18)H(13)NO(2)S, has two independent mol­ecules (A and B) with similar conformations in the asymmetric unit. Both phenothia­zine moieties have a butterfly structure [dihedral angles between benzene rings = 155.17 (7) and 161.71 (7)°, respectively], and the central six-membered rings have a boat form. In the crystal, the A and B mol­ecules stack alternately along the b axis. The A and B mol­ecules are linked by O—H⋯O=S hydrogen bonds, forming zigzag chains along [10-1]. International Union of Crystallography 2012-06-27 /pmc/articles/PMC3394009/ /pubmed/22798874 http://dx.doi.org/10.1107/S1600536812027511 Text en © Tabata and Okuno 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Tabata, Hideyuki
Okuno, Tsunehisa
10-(6-Hy­droxy­hexa-2,4-diyn-1-yl)-10H-phenothia­zine 5-oxide
title 10-(6-Hy­droxy­hexa-2,4-diyn-1-yl)-10H-phenothia­zine 5-oxide
title_full 10-(6-Hy­droxy­hexa-2,4-diyn-1-yl)-10H-phenothia­zine 5-oxide
title_fullStr 10-(6-Hy­droxy­hexa-2,4-diyn-1-yl)-10H-phenothia­zine 5-oxide
title_full_unstemmed 10-(6-Hy­droxy­hexa-2,4-diyn-1-yl)-10H-phenothia­zine 5-oxide
title_short 10-(6-Hy­droxy­hexa-2,4-diyn-1-yl)-10H-phenothia­zine 5-oxide
title_sort 10-(6-hy­droxy­hexa-2,4-diyn-1-yl)-10h-phenothia­zine 5-oxide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3394009/
https://www.ncbi.nlm.nih.gov/pubmed/22798874
http://dx.doi.org/10.1107/S1600536812027511
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