(Z)-4-Chloro-N-(1-{2-[3-(4-chloro­benzoyl)ureido]eth­yl}imidazolidin-2-yl­idene)benzamide

The title compound, C(20)H(19)Cl(2)N(5)O(2)S, was obtained from the reaction of 4-chloro­benzoyl isothio­cyanate with diethyl­ene­triamine. The imidazolidine ring is slightly twisted with an N—C—C—N torsion angle of 15.4 (4)°, while the thio­urea moiety maintains its trans–cis geometry. The mol­ecul...

Descripción completa

Detalles Bibliográficos
Autores principales: Adan, Dalina, Sapari, Suhaila, Halim, Siti Nadiah, Yamin, Bohari M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3394018/
https://www.ncbi.nlm.nih.gov/pubmed/22798883
http://dx.doi.org/10.1107/S1600536812028218
_version_ 1782237804574539776
author Adan, Dalina
Sapari, Suhaila
Halim, Siti Nadiah
Yamin, Bohari M.
author_facet Adan, Dalina
Sapari, Suhaila
Halim, Siti Nadiah
Yamin, Bohari M.
author_sort Adan, Dalina
collection PubMed
description The title compound, C(20)H(19)Cl(2)N(5)O(2)S, was obtained from the reaction of 4-chloro­benzoyl isothio­cyanate with diethyl­ene­triamine. The imidazolidine ring is slightly twisted with an N—C—C—N torsion angle of 15.4 (4)°, while the thio­urea moiety maintains its trans–cis geometry. The mol­ecule is stabilized by intramolecular N—H⋯O hydrogen bonds. The crystal structure features N—H⋯O, N—H⋯S and C—H⋯O hydrogen bonds and π–π interactions between benzene rings with a centroid–centroid distance of 3.607 (3) Å.
format Online
Article
Text
id pubmed-3394018
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-33940182012-07-13 (Z)-4-Chloro-N-(1-{2-[3-(4-chloro­benzoyl)ureido]eth­yl}imidazolidin-2-yl­idene)benzamide Adan, Dalina Sapari, Suhaila Halim, Siti Nadiah Yamin, Bohari M. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(20)H(19)Cl(2)N(5)O(2)S, was obtained from the reaction of 4-chloro­benzoyl isothio­cyanate with diethyl­ene­triamine. The imidazolidine ring is slightly twisted with an N—C—C—N torsion angle of 15.4 (4)°, while the thio­urea moiety maintains its trans–cis geometry. The mol­ecule is stabilized by intramolecular N—H⋯O hydrogen bonds. The crystal structure features N—H⋯O, N—H⋯S and C—H⋯O hydrogen bonds and π–π interactions between benzene rings with a centroid–centroid distance of 3.607 (3) Å. International Union of Crystallography 2012-06-27 /pmc/articles/PMC3394018/ /pubmed/22798883 http://dx.doi.org/10.1107/S1600536812028218 Text en © Adan et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Adan, Dalina
Sapari, Suhaila
Halim, Siti Nadiah
Yamin, Bohari M.
(Z)-4-Chloro-N-(1-{2-[3-(4-chloro­benzoyl)ureido]eth­yl}imidazolidin-2-yl­idene)benzamide
title (Z)-4-Chloro-N-(1-{2-[3-(4-chloro­benzoyl)ureido]eth­yl}imidazolidin-2-yl­idene)benzamide
title_full (Z)-4-Chloro-N-(1-{2-[3-(4-chloro­benzoyl)ureido]eth­yl}imidazolidin-2-yl­idene)benzamide
title_fullStr (Z)-4-Chloro-N-(1-{2-[3-(4-chloro­benzoyl)ureido]eth­yl}imidazolidin-2-yl­idene)benzamide
title_full_unstemmed (Z)-4-Chloro-N-(1-{2-[3-(4-chloro­benzoyl)ureido]eth­yl}imidazolidin-2-yl­idene)benzamide
title_short (Z)-4-Chloro-N-(1-{2-[3-(4-chloro­benzoyl)ureido]eth­yl}imidazolidin-2-yl­idene)benzamide
title_sort (z)-4-chloro-n-(1-{2-[3-(4-chloro­benzoyl)ureido]eth­yl}imidazolidin-2-yl­idene)benzamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3394018/
https://www.ncbi.nlm.nih.gov/pubmed/22798883
http://dx.doi.org/10.1107/S1600536812028218
work_keys_str_mv AT adandalina z4chloron1234chlorobenzoylureidoethylimidazolidin2ylidenebenzamide
AT saparisuhaila z4chloron1234chlorobenzoylureidoethylimidazolidin2ylidenebenzamide
AT halimsitinadiah z4chloron1234chlorobenzoylureidoethylimidazolidin2ylidenebenzamide
AT yaminboharim z4chloron1234chlorobenzoylureidoethylimidazolidin2ylidenebenzamide

Ejemplares similares