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Ethyl 2,7,7-trimethyl-5-oxo-4-phenyl-1,4,5,6,7,8-hexa­hydro­quinoline-3-carboxyl­ate

In the title compound, C(21)H(25)NO(3), the hydro­pyridine ring that constitutes a part of the hexa­hydro­quinoline fused-ring system adopts a sofa conformation; the methine C atom deviates from the least-squares plane defined by the remaining five non-H atoms (r.m.s. deviation = 0.088 Å) by 0.454 (...

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Detalles Bibliográficos
Autores principales: Kurbanova, Malahat M., Huseynov, Elnur Z., Gurbanov, Atash V., Maharramov, Abel M., Ng, Seik Weng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3394024/
https://www.ncbi.nlm.nih.gov/pubmed/22798889
http://dx.doi.org/10.1107/S1600536812028371
Descripción
Sumario:In the title compound, C(21)H(25)NO(3), the hydro­pyridine ring that constitutes a part of the hexa­hydro­quinoline fused-ring system adopts a sofa conformation; the methine C atom deviates from the least-squares plane defined by the remaining five non-H atoms (r.m.s. deviation = 0.088 Å) by 0.454 (3) Å. The phenyl ring is aligned at 85.5 (1)° with respect to this mean plane. In the crystal, adjacent molecules are linked via an N—H⋯O hydrogen bond, involving the amino group and the carbonyl O atom of the fused-ring system, forming chains running along [100]. The ethyl group is disordered over two positions in a 0.609 (6):0.391 (6) ratio.