8-O-Ethyl­yunaconitine from the roots of Aconitum carmichaeli Debx.

The title compound [systematic name: (1α,3α,6α,8β,13β,14α,16β)-20-ethyl-8-eth­oxy-3,13-dihy­droxy-1,6,16-trimeth­oxy-4-(meth­oxy­meth­yl)aconitan-14-yl 4-meth­oxy­benzoate], C(35)H(51)NO(10), was isolated from roots of Aconitum carmichaeli Debx., which is a typical C(19)-diterpenoid alkaloid. The mo...

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Detalles Bibliográficos
Autores principales: Wu, San-Lin, Liu, Fang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3394029/
https://www.ncbi.nlm.nih.gov/pubmed/22798894
http://dx.doi.org/10.1107/S1600536812026463
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author Wu, San-Lin
Liu, Fang
author_facet Wu, San-Lin
Liu, Fang
author_sort Wu, San-Lin
collection PubMed
description The title compound [systematic name: (1α,3α,6α,8β,13β,14α,16β)-20-ethyl-8-eth­oxy-3,13-dihy­droxy-1,6,16-trimeth­oxy-4-(meth­oxy­meth­yl)aconitan-14-yl 4-meth­oxy­benzoate], C(35)H(51)NO(10), was isolated from roots of Aconitum carmichaeli Debx., which is a typical C(19)-diterpenoid alkaloid. The mol­ecule has an aconitane carbon skeleton with four six-membered rings and two five-membered rings. The six-membered rings adopt chair conformations or boat conformations, while the five-membered rings have envelope conformations. Intra­molecular O—H⋯O and O—H⋯N hydrogen bonds help to stabilize the mol­ecular structure. Weak inter­molecular C—H⋯O inter­actions occur in the crystal structure.
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spelling pubmed-33940292012-07-13 8-O-Ethyl­yunaconitine from the roots of Aconitum carmichaeli Debx. Wu, San-Lin Liu, Fang Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound [systematic name: (1α,3α,6α,8β,13β,14α,16β)-20-ethyl-8-eth­oxy-3,13-dihy­droxy-1,6,16-trimeth­oxy-4-(meth­oxy­meth­yl)aconitan-14-yl 4-meth­oxy­benzoate], C(35)H(51)NO(10), was isolated from roots of Aconitum carmichaeli Debx., which is a typical C(19)-diterpenoid alkaloid. The mol­ecule has an aconitane carbon skeleton with four six-membered rings and two five-membered rings. The six-membered rings adopt chair conformations or boat conformations, while the five-membered rings have envelope conformations. Intra­molecular O—H⋯O and O—H⋯N hydrogen bonds help to stabilize the mol­ecular structure. Weak inter­molecular C—H⋯O inter­actions occur in the crystal structure. International Union of Crystallography 2012-06-30 /pmc/articles/PMC3394029/ /pubmed/22798894 http://dx.doi.org/10.1107/S1600536812026463 Text en © Wu and Liu 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Wu, San-Lin
Liu, Fang
8-O-Ethyl­yunaconitine from the roots of Aconitum carmichaeli Debx.
title 8-O-Ethyl­yunaconitine from the roots of Aconitum carmichaeli Debx.
title_full 8-O-Ethyl­yunaconitine from the roots of Aconitum carmichaeli Debx.
title_fullStr 8-O-Ethyl­yunaconitine from the roots of Aconitum carmichaeli Debx.
title_full_unstemmed 8-O-Ethyl­yunaconitine from the roots of Aconitum carmichaeli Debx.
title_short 8-O-Ethyl­yunaconitine from the roots of Aconitum carmichaeli Debx.
title_sort 8-o-ethyl­yunaconitine from the roots of aconitum carmichaeli debx.
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3394029/
https://www.ncbi.nlm.nih.gov/pubmed/22798894
http://dx.doi.org/10.1107/S1600536812026463
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