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4,6-Dichloro-2-[(E)-(2-{[(E)-3,5-dichloro-2-oxidobenzyl­idene]aza­nium­yl}eth­yl)iminiumylmeth­yl]phenolate

The asymmetric unit of the title compound, C(16)H(12)Cl(4)N(2)O(2), comprises half of a potentially tetra­dentate Schiff base ligand, located about a twofold rotation axis which bis­ects the central C—C bond of the ethane-1,2-diamine group. In the solid state, the compound exists in the zwitterionic...

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Detalles Bibliográficos
Autores principales: Kia, Reza, Kargar, Hadi, Adabi Ardakani, Amir, Tahir, Muhammad Nawaz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3394033/
https://www.ncbi.nlm.nih.gov/pubmed/22798898
http://dx.doi.org/10.1107/S160053681202870X
Descripción
Sumario:The asymmetric unit of the title compound, C(16)H(12)Cl(4)N(2)O(2), comprises half of a potentially tetra­dentate Schiff base ligand, located about a twofold rotation axis which bis­ects the central C—C bond of the ethane-1,2-diamine group. In the solid state, the compound exists in the zwitterionic form. There are two intra­molecular N—H⋯O hydrogen bonds making S(6) ring motifs. In the crystal, mol­ecules are linked by C—H⋯O hydrogen bonds, forming two-dimensional frameworks which lie parallel to (100). There are also short Cl⋯Cl [3.4395 (9) Å] contacts present.