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4,6-Dichloro-2-[(E)-(2-{[(E)-3,5-dichloro-2-oxidobenzyl­idene]aza­nium­yl}eth­yl)iminiumylmeth­yl]phenolate

The asymmetric unit of the title compound, C(16)H(12)Cl(4)N(2)O(2), comprises half of a potentially tetra­dentate Schiff base ligand, located about a twofold rotation axis which bis­ects the central C—C bond of the ethane-1,2-diamine group. In the solid state, the compound exists in the zwitterionic...

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Autores principales: Kia, Reza, Kargar, Hadi, Adabi Ardakani, Amir, Tahir, Muhammad Nawaz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3394033/
https://www.ncbi.nlm.nih.gov/pubmed/22798898
http://dx.doi.org/10.1107/S160053681202870X
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author Kia, Reza
Kargar, Hadi
Adabi Ardakani, Amir
Tahir, Muhammad Nawaz
author_facet Kia, Reza
Kargar, Hadi
Adabi Ardakani, Amir
Tahir, Muhammad Nawaz
author_sort Kia, Reza
collection PubMed
description The asymmetric unit of the title compound, C(16)H(12)Cl(4)N(2)O(2), comprises half of a potentially tetra­dentate Schiff base ligand, located about a twofold rotation axis which bis­ects the central C—C bond of the ethane-1,2-diamine group. In the solid state, the compound exists in the zwitterionic form. There are two intra­molecular N—H⋯O hydrogen bonds making S(6) ring motifs. In the crystal, mol­ecules are linked by C—H⋯O hydrogen bonds, forming two-dimensional frameworks which lie parallel to (100). There are also short Cl⋯Cl [3.4395 (9) Å] contacts present.
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spelling pubmed-33940332012-07-13 4,6-Dichloro-2-[(E)-(2-{[(E)-3,5-dichloro-2-oxidobenzyl­idene]aza­nium­yl}eth­yl)iminiumylmeth­yl]phenolate Kia, Reza Kargar, Hadi Adabi Ardakani, Amir Tahir, Muhammad Nawaz Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(16)H(12)Cl(4)N(2)O(2), comprises half of a potentially tetra­dentate Schiff base ligand, located about a twofold rotation axis which bis­ects the central C—C bond of the ethane-1,2-diamine group. In the solid state, the compound exists in the zwitterionic form. There are two intra­molecular N—H⋯O hydrogen bonds making S(6) ring motifs. In the crystal, mol­ecules are linked by C—H⋯O hydrogen bonds, forming two-dimensional frameworks which lie parallel to (100). There are also short Cl⋯Cl [3.4395 (9) Å] contacts present. International Union of Crystallography 2012-06-30 /pmc/articles/PMC3394033/ /pubmed/22798898 http://dx.doi.org/10.1107/S160053681202870X Text en © Kargar et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Kia, Reza
Kargar, Hadi
Adabi Ardakani, Amir
Tahir, Muhammad Nawaz
4,6-Dichloro-2-[(E)-(2-{[(E)-3,5-dichloro-2-oxidobenzyl­idene]aza­nium­yl}eth­yl)iminiumylmeth­yl]phenolate
title 4,6-Dichloro-2-[(E)-(2-{[(E)-3,5-dichloro-2-oxidobenzyl­idene]aza­nium­yl}eth­yl)iminiumylmeth­yl]phenolate
title_full 4,6-Dichloro-2-[(E)-(2-{[(E)-3,5-dichloro-2-oxidobenzyl­idene]aza­nium­yl}eth­yl)iminiumylmeth­yl]phenolate
title_fullStr 4,6-Dichloro-2-[(E)-(2-{[(E)-3,5-dichloro-2-oxidobenzyl­idene]aza­nium­yl}eth­yl)iminiumylmeth­yl]phenolate
title_full_unstemmed 4,6-Dichloro-2-[(E)-(2-{[(E)-3,5-dichloro-2-oxidobenzyl­idene]aza­nium­yl}eth­yl)iminiumylmeth­yl]phenolate
title_short 4,6-Dichloro-2-[(E)-(2-{[(E)-3,5-dichloro-2-oxidobenzyl­idene]aza­nium­yl}eth­yl)iminiumylmeth­yl]phenolate
title_sort 4,6-dichloro-2-[(e)-(2-{[(e)-3,5-dichloro-2-oxidobenzyl­idene]aza­nium­yl}eth­yl)iminiumylmeth­yl]phenolate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3394033/
https://www.ncbi.nlm.nih.gov/pubmed/22798898
http://dx.doi.org/10.1107/S160053681202870X
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