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4,6-Dichloro-2-((E)-{4-[(E)-3,5-dichloro-2-hydroxybenzylideneamino]butylimino}methyl)phenol
The asymmetric unit of the title compound, C(18)H(16)Cl(4)N(2)O(2), comprises half of a potentially tetradentate Schiff base ligand. It is located about a twofold rotation axis that bisects the central C—C bond of the butane-1,4-diamine group. There are two intramolecular O—H⋯N hydrogen bonds mak...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3394034/ https://www.ncbi.nlm.nih.gov/pubmed/22798899 http://dx.doi.org/10.1107/S1600536812028693 |
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author | Kargar, Hadi Kia, Reza Adabi Ardakani, Amir Tahir, Muhammad Nawaz |
author_facet | Kargar, Hadi Kia, Reza Adabi Ardakani, Amir Tahir, Muhammad Nawaz |
author_sort | Kargar, Hadi |
collection | PubMed |
description | The asymmetric unit of the title compound, C(18)H(16)Cl(4)N(2)O(2), comprises half of a potentially tetradentate Schiff base ligand. It is located about a twofold rotation axis that bisects the central C—C bond of the butane-1,4-diamine group. There are two intramolecular O—H⋯N hydrogen bonds making S(6) ring motifs. In the crystal, molecules are linked by pairs of weak C—H⋯Cl interactions, forming inversion dimers, which are further connected by C—H⋯O hydrogen bonds into two-dimensional frameworks that lie parallel to (001). |
format | Online Article Text |
id | pubmed-3394034 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33940342012-07-13 4,6-Dichloro-2-((E)-{4-[(E)-3,5-dichloro-2-hydroxybenzylideneamino]butylimino}methyl)phenol Kargar, Hadi Kia, Reza Adabi Ardakani, Amir Tahir, Muhammad Nawaz Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(18)H(16)Cl(4)N(2)O(2), comprises half of a potentially tetradentate Schiff base ligand. It is located about a twofold rotation axis that bisects the central C—C bond of the butane-1,4-diamine group. There are two intramolecular O—H⋯N hydrogen bonds making S(6) ring motifs. In the crystal, molecules are linked by pairs of weak C—H⋯Cl interactions, forming inversion dimers, which are further connected by C—H⋯O hydrogen bonds into two-dimensional frameworks that lie parallel to (001). International Union of Crystallography 2012-06-30 /pmc/articles/PMC3394034/ /pubmed/22798899 http://dx.doi.org/10.1107/S1600536812028693 Text en © Kargar et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Kargar, Hadi Kia, Reza Adabi Ardakani, Amir Tahir, Muhammad Nawaz 4,6-Dichloro-2-((E)-{4-[(E)-3,5-dichloro-2-hydroxybenzylideneamino]butylimino}methyl)phenol |
title | 4,6-Dichloro-2-((E)-{4-[(E)-3,5-dichloro-2-hydroxybenzylideneamino]butylimino}methyl)phenol |
title_full | 4,6-Dichloro-2-((E)-{4-[(E)-3,5-dichloro-2-hydroxybenzylideneamino]butylimino}methyl)phenol |
title_fullStr | 4,6-Dichloro-2-((E)-{4-[(E)-3,5-dichloro-2-hydroxybenzylideneamino]butylimino}methyl)phenol |
title_full_unstemmed | 4,6-Dichloro-2-((E)-{4-[(E)-3,5-dichloro-2-hydroxybenzylideneamino]butylimino}methyl)phenol |
title_short | 4,6-Dichloro-2-((E)-{4-[(E)-3,5-dichloro-2-hydroxybenzylideneamino]butylimino}methyl)phenol |
title_sort | 4,6-dichloro-2-((e)-{4-[(e)-3,5-dichloro-2-hydroxybenzylideneamino]butylimino}methyl)phenol |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3394034/ https://www.ncbi.nlm.nih.gov/pubmed/22798899 http://dx.doi.org/10.1107/S1600536812028693 |
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