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4,6-Dichloro-2-((E)-{4-[(E)-3,5-dichloro-2-hy­droxy­benzyl­idene­amino]­butyl­imino}­meth­yl)phenol

The asymmetric unit of the title compound, C(18)H(16)Cl(4)N(2)O(2), comprises half of a potentially tetra­dentate Schiff base ligand. It is located about a twofold rotation axis that bis­ects the central C—C bond of the butane-1,4-diamine group. There are two intra­molecular O—H⋯N hydrogen bonds mak...

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Detalles Bibliográficos
Autores principales: Kargar, Hadi, Kia, Reza, Adabi Ardakani, Amir, Tahir, Muhammad Nawaz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3394034/
https://www.ncbi.nlm.nih.gov/pubmed/22798899
http://dx.doi.org/10.1107/S1600536812028693
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author Kargar, Hadi
Kia, Reza
Adabi Ardakani, Amir
Tahir, Muhammad Nawaz
author_facet Kargar, Hadi
Kia, Reza
Adabi Ardakani, Amir
Tahir, Muhammad Nawaz
author_sort Kargar, Hadi
collection PubMed
description The asymmetric unit of the title compound, C(18)H(16)Cl(4)N(2)O(2), comprises half of a potentially tetra­dentate Schiff base ligand. It is located about a twofold rotation axis that bis­ects the central C—C bond of the butane-1,4-diamine group. There are two intra­molecular O—H⋯N hydrogen bonds making S(6) ring motifs. In the crystal, mol­ecules are linked by pairs of weak C—H⋯Cl inter­actions, forming inversion dimers, which are further connected by C—H⋯O hydrogen bonds into two-dimensional frameworks that lie parallel to (001).
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spelling pubmed-33940342012-07-13 4,6-Dichloro-2-((E)-{4-[(E)-3,5-dichloro-2-hy­droxy­benzyl­idene­amino]­butyl­imino}­meth­yl)phenol Kargar, Hadi Kia, Reza Adabi Ardakani, Amir Tahir, Muhammad Nawaz Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(18)H(16)Cl(4)N(2)O(2), comprises half of a potentially tetra­dentate Schiff base ligand. It is located about a twofold rotation axis that bis­ects the central C—C bond of the butane-1,4-diamine group. There are two intra­molecular O—H⋯N hydrogen bonds making S(6) ring motifs. In the crystal, mol­ecules are linked by pairs of weak C—H⋯Cl inter­actions, forming inversion dimers, which are further connected by C—H⋯O hydrogen bonds into two-dimensional frameworks that lie parallel to (001). International Union of Crystallography 2012-06-30 /pmc/articles/PMC3394034/ /pubmed/22798899 http://dx.doi.org/10.1107/S1600536812028693 Text en © Kargar et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Kargar, Hadi
Kia, Reza
Adabi Ardakani, Amir
Tahir, Muhammad Nawaz
4,6-Dichloro-2-((E)-{4-[(E)-3,5-dichloro-2-hy­droxy­benzyl­idene­amino]­butyl­imino}­meth­yl)phenol
title 4,6-Dichloro-2-((E)-{4-[(E)-3,5-dichloro-2-hy­droxy­benzyl­idene­amino]­butyl­imino}­meth­yl)phenol
title_full 4,6-Dichloro-2-((E)-{4-[(E)-3,5-dichloro-2-hy­droxy­benzyl­idene­amino]­butyl­imino}­meth­yl)phenol
title_fullStr 4,6-Dichloro-2-((E)-{4-[(E)-3,5-dichloro-2-hy­droxy­benzyl­idene­amino]­butyl­imino}­meth­yl)phenol
title_full_unstemmed 4,6-Dichloro-2-((E)-{4-[(E)-3,5-dichloro-2-hy­droxy­benzyl­idene­amino]­butyl­imino}­meth­yl)phenol
title_short 4,6-Dichloro-2-((E)-{4-[(E)-3,5-dichloro-2-hy­droxy­benzyl­idene­amino]­butyl­imino}­meth­yl)phenol
title_sort 4,6-dichloro-2-((e)-{4-[(e)-3,5-dichloro-2-hy­droxy­benzyl­idene­amino]­butyl­imino}­meth­yl)phenol
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3394034/
https://www.ncbi.nlm.nih.gov/pubmed/22798899
http://dx.doi.org/10.1107/S1600536812028693
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