2-[(1H-Benzimidazol-2-yl)sulfan­yl]-1-phenyl­ethanone

The title compound, C(15)H(12)N(2)OS, adopts a twisted V-shape, with the S atom as the pivot. The benzimidazole ring system [maximum deviation = 0.015 (1) Å] makes a dihedral angle of 78.56 (7)° with the phenyl ring. The O atom of the ketone group is close to coplanar with its adjacent ring [O—C—C—C...

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Detalles Bibliográficos
Autores principales: Abdel-Aziz, Hatem A., Chia, Tze Shyang, Fun, Hoong-Kun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3394045/
https://www.ncbi.nlm.nih.gov/pubmed/22798910
http://dx.doi.org/10.1107/S1600536812028747
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author Abdel-Aziz, Hatem A.
Chia, Tze Shyang
Fun, Hoong-Kun
author_facet Abdel-Aziz, Hatem A.
Chia, Tze Shyang
Fun, Hoong-Kun
author_sort Abdel-Aziz, Hatem A.
collection PubMed
description The title compound, C(15)H(12)N(2)OS, adopts a twisted V-shape, with the S atom as the pivot. The benzimidazole ring system [maximum deviation = 0.015 (1) Å] makes a dihedral angle of 78.56 (7)° with the phenyl ring. The O atom of the ketone group is close to coplanar with its adjacent ring [O—C—C—C torsion angle = 11.0 (2)°]. In the crystal, mol­ecules are linked by N—H⋯N hydrogen bonds into an infinite chain along [001]. The crystal packing also features a C—H⋯π inter­action.
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spelling pubmed-33940452012-07-13 2-[(1H-Benzimidazol-2-yl)sulfan­yl]-1-phenyl­ethanone Abdel-Aziz, Hatem A. Chia, Tze Shyang Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(15)H(12)N(2)OS, adopts a twisted V-shape, with the S atom as the pivot. The benzimidazole ring system [maximum deviation = 0.015 (1) Å] makes a dihedral angle of 78.56 (7)° with the phenyl ring. The O atom of the ketone group is close to coplanar with its adjacent ring [O—C—C—C torsion angle = 11.0 (2)°]. In the crystal, mol­ecules are linked by N—H⋯N hydrogen bonds into an infinite chain along [001]. The crystal packing also features a C—H⋯π inter­action. International Union of Crystallography 2012-06-30 /pmc/articles/PMC3394045/ /pubmed/22798910 http://dx.doi.org/10.1107/S1600536812028747 Text en © Abdel-Aziz et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Abdel-Aziz, Hatem A.
Chia, Tze Shyang
Fun, Hoong-Kun
2-[(1H-Benzimidazol-2-yl)sulfan­yl]-1-phenyl­ethanone
title 2-[(1H-Benzimidazol-2-yl)sulfan­yl]-1-phenyl­ethanone
title_full 2-[(1H-Benzimidazol-2-yl)sulfan­yl]-1-phenyl­ethanone
title_fullStr 2-[(1H-Benzimidazol-2-yl)sulfan­yl]-1-phenyl­ethanone
title_full_unstemmed 2-[(1H-Benzimidazol-2-yl)sulfan­yl]-1-phenyl­ethanone
title_short 2-[(1H-Benzimidazol-2-yl)sulfan­yl]-1-phenyl­ethanone
title_sort 2-[(1h-benzimidazol-2-yl)sulfan­yl]-1-phenyl­ethanone
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3394045/
https://www.ncbi.nlm.nih.gov/pubmed/22798910
http://dx.doi.org/10.1107/S1600536812028747
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