1-Chloro-1-[(Z)-2-phenyl­hydrazin-1-yl­idene]propan-2-one

The title compound, C(9)H(9)ClN(2)O, is close to planar (r.m.s. deviation for the non-H atoms = 0.0446 Å); it exists in a cis conformation with respect to the C=N double bond. In the crystal, the ketone O atom accepts both N—H⋯O and C—H⋯O hydrogen bonds, which leads to [010] infinite chains incorpor...

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Detalles Bibliográficos
Autores principales: Abdel-Aziz, Hatem A., Chia, Tze Shyang, Fun, Hoong-Kun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3394046/
https://www.ncbi.nlm.nih.gov/pubmed/22798911
http://dx.doi.org/10.1107/S1600536812028759
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author Abdel-Aziz, Hatem A.
Chia, Tze Shyang
Fun, Hoong-Kun
author_facet Abdel-Aziz, Hatem A.
Chia, Tze Shyang
Fun, Hoong-Kun
author_sort Abdel-Aziz, Hatem A.
collection PubMed
description The title compound, C(9)H(9)ClN(2)O, is close to planar (r.m.s. deviation for the non-H atoms = 0.0446 Å); it exists in a cis conformation with respect to the C=N double bond. In the crystal, the ketone O atom accepts both N—H⋯O and C—H⋯O hydrogen bonds, which leads to [010] infinite chains incorporating R (2) (1)(6) loops. The crystal structure also features a C—H⋯π inter­action.
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spelling pubmed-33940462012-07-13 1-Chloro-1-[(Z)-2-phenyl­hydrazin-1-yl­idene]propan-2-one Abdel-Aziz, Hatem A. Chia, Tze Shyang Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(9)H(9)ClN(2)O, is close to planar (r.m.s. deviation for the non-H atoms = 0.0446 Å); it exists in a cis conformation with respect to the C=N double bond. In the crystal, the ketone O atom accepts both N—H⋯O and C—H⋯O hydrogen bonds, which leads to [010] infinite chains incorporating R (2) (1)(6) loops. The crystal structure also features a C—H⋯π inter­action. International Union of Crystallography 2012-06-30 /pmc/articles/PMC3394046/ /pubmed/22798911 http://dx.doi.org/10.1107/S1600536812028759 Text en © Abdel-Aziz et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Abdel-Aziz, Hatem A.
Chia, Tze Shyang
Fun, Hoong-Kun
1-Chloro-1-[(Z)-2-phenyl­hydrazin-1-yl­idene]propan-2-one
title 1-Chloro-1-[(Z)-2-phenyl­hydrazin-1-yl­idene]propan-2-one
title_full 1-Chloro-1-[(Z)-2-phenyl­hydrazin-1-yl­idene]propan-2-one
title_fullStr 1-Chloro-1-[(Z)-2-phenyl­hydrazin-1-yl­idene]propan-2-one
title_full_unstemmed 1-Chloro-1-[(Z)-2-phenyl­hydrazin-1-yl­idene]propan-2-one
title_short 1-Chloro-1-[(Z)-2-phenyl­hydrazin-1-yl­idene]propan-2-one
title_sort 1-chloro-1-[(z)-2-phenyl­hydrazin-1-yl­idene]propan-2-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3394046/
https://www.ncbi.nlm.nih.gov/pubmed/22798911
http://dx.doi.org/10.1107/S1600536812028759
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AT chiatzeshyang 1chloro1z2phenylhydrazin1ylidenepropan2one
AT funhoongkun 1chloro1z2phenylhydrazin1ylidenepropan2one

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