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Cyclohexylammonium acetate–N,N′,N′′-tricyclohexylphosphoric triamide (1/1)
In the phosphoric triamide molecule of the title compound, C(6)H(14)N(+)·C(2)H(3)O(2) (−)·C(18)H(36)N(3)OP, the P atom displays a distorted tetrahedral geometry and the cyclohexyl rings adopt chair conformations with the NH groups in equatorial positions. In the crystal, the cations, anions and...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3394049/ https://www.ncbi.nlm.nih.gov/pubmed/22798914 http://dx.doi.org/10.1107/S1600536812028589 |
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| author | Pourayoubi, Mehrdad Keikha, Mojtaba Rheingold, Arnold L. Golen, James A. |
| author_facet | Pourayoubi, Mehrdad Keikha, Mojtaba Rheingold, Arnold L. Golen, James A. |
| author_sort | Pourayoubi, Mehrdad |
| collection | PubMed |
| description | In the phosphoric triamide molecule of the title compound, C(6)H(14)N(+)·C(2)H(3)O(2) (−)·C(18)H(36)N(3)OP, the P atom displays a distorted tetrahedral geometry and the cyclohexyl rings adopt chair conformations with the NH groups in equatorial positions. In the crystal, the cations, anions and phosphoric triamide molecules are linked via N—H⋯O hydrogen bonds into a two-dimensional array parallel to the bc plane. The O atom of the P(O) group acts as a double-hydrogen-bond acceptor. |
| format | Online Article Text |
| id | pubmed-3394049 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-33940492012-07-13 Cyclohexylammonium acetate–N,N′,N′′-tricyclohexylphosphoric triamide (1/1) Pourayoubi, Mehrdad Keikha, Mojtaba Rheingold, Arnold L. Golen, James A. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the phosphoric triamide molecule of the title compound, C(6)H(14)N(+)·C(2)H(3)O(2) (−)·C(18)H(36)N(3)OP, the P atom displays a distorted tetrahedral geometry and the cyclohexyl rings adopt chair conformations with the NH groups in equatorial positions. In the crystal, the cations, anions and phosphoric triamide molecules are linked via N—H⋯O hydrogen bonds into a two-dimensional array parallel to the bc plane. The O atom of the P(O) group acts as a double-hydrogen-bond acceptor. International Union of Crystallography 2012-06-30 /pmc/articles/PMC3394049/ /pubmed/22798914 http://dx.doi.org/10.1107/S1600536812028589 Text en © Pourayoubi et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Organic Papers Pourayoubi, Mehrdad Keikha, Mojtaba Rheingold, Arnold L. Golen, James A. Cyclohexylammonium acetate–N,N′,N′′-tricyclohexylphosphoric triamide (1/1) |
| title | Cyclohexylammonium acetate–N,N′,N′′-tricyclohexylphosphoric triamide (1/1) |
| title_full | Cyclohexylammonium acetate–N,N′,N′′-tricyclohexylphosphoric triamide (1/1) |
| title_fullStr | Cyclohexylammonium acetate–N,N′,N′′-tricyclohexylphosphoric triamide (1/1) |
| title_full_unstemmed | Cyclohexylammonium acetate–N,N′,N′′-tricyclohexylphosphoric triamide (1/1) |
| title_short | Cyclohexylammonium acetate–N,N′,N′′-tricyclohexylphosphoric triamide (1/1) |
| title_sort | cyclohexylammonium acetate–n,n′,n′′-tricyclohexylphosphoric triamide (1/1) |
| topic | Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3394049/ https://www.ncbi.nlm.nih.gov/pubmed/22798914 http://dx.doi.org/10.1107/S1600536812028589 |
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