Cargando…

(4E)-N-[(2-Bromo­phen­yl)meth­oxy]-1,3-dimethyl-2,6-diphenyl­piperidin-4-imine

In the title compound, C(26)H(27)BrN(2)O, the piperidine ring has a chair conformation and all ring substituents occupy equatorial positions, apart from the double-bonded N atom, which occupies a bis­ectional position. The dihedral angle formed between the phenyl rings is 61.18 (19)°, and the phenyl...

Descripción completa

Detalles Bibliográficos
Autores principales: Ramalingan, Chennan, Ng, Seik Weng, Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3394050/
https://www.ncbi.nlm.nih.gov/pubmed/22798915
http://dx.doi.org/10.1107/S1600536812028887
_version_ 1782237811806568448
author Ramalingan, Chennan
Ng, Seik Weng
Tiekink, Edward R. T.
author_facet Ramalingan, Chennan
Ng, Seik Weng
Tiekink, Edward R. T.
author_sort Ramalingan, Chennan
collection PubMed
description In the title compound, C(26)H(27)BrN(2)O, the piperidine ring has a chair conformation and all ring substituents occupy equatorial positions, apart from the double-bonded N atom, which occupies a bis­ectional position. The dihedral angle formed between the phenyl rings is 61.18 (19)°, and the phenyl rings form dihedral angles of 49.78 (19) and 69.2 (18)° with the bromo­benzene ring. The latter is coplanar with the meth­oxy(methyl­idene)amine fragment [N—O—C—C torsion angle = −171.7 (2)°]. Linear supra­molecular chains, approximately along [112], sustained by C—H⋯π inter­actions, feature in the crystal packing.
format Online
Article
Text
id pubmed-3394050
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-33940502012-07-13 (4E)-N-[(2-Bromo­phen­yl)meth­oxy]-1,3-dimethyl-2,6-diphenyl­piperidin-4-imine Ramalingan, Chennan Ng, Seik Weng Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(26)H(27)BrN(2)O, the piperidine ring has a chair conformation and all ring substituents occupy equatorial positions, apart from the double-bonded N atom, which occupies a bis­ectional position. The dihedral angle formed between the phenyl rings is 61.18 (19)°, and the phenyl rings form dihedral angles of 49.78 (19) and 69.2 (18)° with the bromo­benzene ring. The latter is coplanar with the meth­oxy(methyl­idene)amine fragment [N—O—C—C torsion angle = −171.7 (2)°]. Linear supra­molecular chains, approximately along [112], sustained by C—H⋯π inter­actions, feature in the crystal packing. International Union of Crystallography 2012-06-30 /pmc/articles/PMC3394050/ /pubmed/22798915 http://dx.doi.org/10.1107/S1600536812028887 Text en © Ramalingan et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ramalingan, Chennan
Ng, Seik Weng
Tiekink, Edward R. T.
(4E)-N-[(2-Bromo­phen­yl)meth­oxy]-1,3-dimethyl-2,6-diphenyl­piperidin-4-imine
title (4E)-N-[(2-Bromo­phen­yl)meth­oxy]-1,3-dimethyl-2,6-diphenyl­piperidin-4-imine
title_full (4E)-N-[(2-Bromo­phen­yl)meth­oxy]-1,3-dimethyl-2,6-diphenyl­piperidin-4-imine
title_fullStr (4E)-N-[(2-Bromo­phen­yl)meth­oxy]-1,3-dimethyl-2,6-diphenyl­piperidin-4-imine
title_full_unstemmed (4E)-N-[(2-Bromo­phen­yl)meth­oxy]-1,3-dimethyl-2,6-diphenyl­piperidin-4-imine
title_short (4E)-N-[(2-Bromo­phen­yl)meth­oxy]-1,3-dimethyl-2,6-diphenyl­piperidin-4-imine
title_sort (4e)-n-[(2-bromo­phen­yl)meth­oxy]-1,3-dimethyl-2,6-diphenyl­piperidin-4-imine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3394050/
https://www.ncbi.nlm.nih.gov/pubmed/22798915
http://dx.doi.org/10.1107/S1600536812028887
work_keys_str_mv AT ramalinganchennan 4en2bromophenylmethoxy13dimethyl26diphenylpiperidin4imine
AT ngseikweng 4en2bromophenylmethoxy13dimethyl26diphenylpiperidin4imine
AT tiekinkedwardrt 4en2bromophenylmethoxy13dimethyl26diphenylpiperidin4imine