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(4E)-N-[(2-Chlorophenyl)methoxy]-1,3-dimethyl-2,6-diphenylpiperidin-4-imine
In the title compound, C(26)H(27)ClN(2)O, the piperidine ring has a chair conformation and all of the ring substituents at Csp (3) atoms occupy equatorial positions. The dihedral angle formed between the phenyl rings is 48.11 (9)°. The chlorobenzene ring occupies a position orthogonal to the metho...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3394051/ https://www.ncbi.nlm.nih.gov/pubmed/22798916 http://dx.doi.org/10.1107/S1600536812028899 |
Sumario: | In the title compound, C(26)H(27)ClN(2)O, the piperidine ring has a chair conformation and all of the ring substituents at Csp (3) atoms occupy equatorial positions. The dihedral angle formed between the phenyl rings is 48.11 (9)°. The chlorobenzene ring occupies a position orthogonal to the methoxy(methylidene)amine residue [N—O—C—C torsion angle = −87.90 (15)°]. The conformation about the imine C=N bond [1.278 (2) Å] is E, and the chloro substituent is anti to the piperidine N atom. Helical supramolecular chains along [010] are sustained by C—H⋯π interactions in the crystal packing. |
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