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(4E)-N-[(2-Chloro­phen­yl)meth­oxy]-1,3-dimethyl-2,6-diphenyl­piperidin-4-imine

In the title compound, C(26)H(27)ClN(2)O, the piperidine ring has a chair conformation and all of the ring substituents at Csp (3) atoms occupy equatorial positions. The dihedral angle formed between the phenyl rings is 48.11 (9)°. The chloro­benzene ring occupies a position orthogonal to the meth­o...

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Detalles Bibliográficos
Autores principales: Ramalingan, Chennan, Ng, Seik Weng, Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3394051/
https://www.ncbi.nlm.nih.gov/pubmed/22798916
http://dx.doi.org/10.1107/S1600536812028899
Descripción
Sumario:In the title compound, C(26)H(27)ClN(2)O, the piperidine ring has a chair conformation and all of the ring substituents at Csp (3) atoms occupy equatorial positions. The dihedral angle formed between the phenyl rings is 48.11 (9)°. The chloro­benzene ring occupies a position orthogonal to the meth­oxy(methyl­idene)amine residue [N—O—C—C torsion angle = −87.90 (15)°]. The conformation about the imine C=N bond [1.278 (2) Å] is E, and the chloro substituent is anti to the piperidine N atom. Helical supra­molecular chains along [010] are sustained by C—H⋯π inter­actions in the crystal packing.