3,3′-Diethyl-1,1′-(1,4-phenyl­ene­dimethyl­ene)diimidazol-3-ium bis­(hexa­fluoro­phosphate)

In the title mol­ecular salt, C(18)H(24)N(4) (2+)·2PF(6) (−), the complete dication is generated by a crystallographic inversion centre. The central benzene ring makes a dihedral angle of 77.19 (9)° with each of the imidazole rings. In the crystal, C—H⋯F inter­actions link the cations and anions int...

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Autores principales: Haque, Rosenani A., Nasri, S. Fatimah, Rosli, Mohd Mustaqim, Fun, Hoong-Kun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3394059/
https://www.ncbi.nlm.nih.gov/pubmed/22798924
http://dx.doi.org/10.1107/S1600536812028966
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author Haque, Rosenani A.
Nasri, S. Fatimah
Rosli, Mohd Mustaqim
Fun, Hoong-Kun
author_facet Haque, Rosenani A.
Nasri, S. Fatimah
Rosli, Mohd Mustaqim
Fun, Hoong-Kun
author_sort Haque, Rosenani A.
collection PubMed
description In the title mol­ecular salt, C(18)H(24)N(4) (2+)·2PF(6) (−), the complete dication is generated by a crystallographic inversion centre. The central benzene ring makes a dihedral angle of 77.19 (9)° with each of the imidazole rings. In the crystal, C—H⋯F inter­actions link the cations and anions into layers lying parallel to the bc plane. The hexa­fluoro­phosphate anion is disordered over two sets of sites in a 0.520 (11):0.480 (11) ratio.
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spelling pubmed-33940592012-07-13 3,3′-Diethyl-1,1′-(1,4-phenyl­ene­dimethyl­ene)diimidazol-3-ium bis­(hexa­fluoro­phosphate) Haque, Rosenani A. Nasri, S. Fatimah Rosli, Mohd Mustaqim Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title mol­ecular salt, C(18)H(24)N(4) (2+)·2PF(6) (−), the complete dication is generated by a crystallographic inversion centre. The central benzene ring makes a dihedral angle of 77.19 (9)° with each of the imidazole rings. In the crystal, C—H⋯F inter­actions link the cations and anions into layers lying parallel to the bc plane. The hexa­fluoro­phosphate anion is disordered over two sets of sites in a 0.520 (11):0.480 (11) ratio. International Union of Crystallography 2012-06-30 /pmc/articles/PMC3394059/ /pubmed/22798924 http://dx.doi.org/10.1107/S1600536812028966 Text en © Haque et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Haque, Rosenani A.
Nasri, S. Fatimah
Rosli, Mohd Mustaqim
Fun, Hoong-Kun
3,3′-Diethyl-1,1′-(1,4-phenyl­ene­dimethyl­ene)diimidazol-3-ium bis­(hexa­fluoro­phosphate)
title 3,3′-Diethyl-1,1′-(1,4-phenyl­ene­dimethyl­ene)diimidazol-3-ium bis­(hexa­fluoro­phosphate)
title_full 3,3′-Diethyl-1,1′-(1,4-phenyl­ene­dimethyl­ene)diimidazol-3-ium bis­(hexa­fluoro­phosphate)
title_fullStr 3,3′-Diethyl-1,1′-(1,4-phenyl­ene­dimethyl­ene)diimidazol-3-ium bis­(hexa­fluoro­phosphate)
title_full_unstemmed 3,3′-Diethyl-1,1′-(1,4-phenyl­ene­dimethyl­ene)diimidazol-3-ium bis­(hexa­fluoro­phosphate)
title_short 3,3′-Diethyl-1,1′-(1,4-phenyl­ene­dimethyl­ene)diimidazol-3-ium bis­(hexa­fluoro­phosphate)
title_sort 3,3′-diethyl-1,1′-(1,4-phenyl­ene­dimethyl­ene)diimidazol-3-ium bis­(hexa­fluoro­phosphate)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3394059/
https://www.ncbi.nlm.nih.gov/pubmed/22798924
http://dx.doi.org/10.1107/S1600536812028966
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