Ethyl (E)-3-hy­droxy-2-{N-[2-(thio­phen-2-yl)ethen­yl]carbamo­yl}but-2-enoate

In the title compound, C(13)H(15)NO(4)S, there are two independent but conformationally similar mol­ecules in the asymmetric unit, both having an E conformation of the side-chain C=C group. Intra­molecular N—H⋯O and O—H⋯O hydrogen-bonding inter­actions are present in both molecules. In the crystal,...

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Detalles Bibliográficos
Autores principales: Liu, Bao-Shuo, Zhao, Sheng-Yin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3394063/
https://www.ncbi.nlm.nih.gov/pubmed/22798928
http://dx.doi.org/10.1107/S1600536812028176
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author Liu, Bao-Shuo
Zhao, Sheng-Yin
author_facet Liu, Bao-Shuo
Zhao, Sheng-Yin
author_sort Liu, Bao-Shuo
collection PubMed
description In the title compound, C(13)H(15)NO(4)S, there are two independent but conformationally similar mol­ecules in the asymmetric unit, both having an E conformation of the side-chain C=C group. Intra­molecular N—H⋯O and O—H⋯O hydrogen-bonding inter­actions are present in both molecules. In the crystal, one of the mol­ecule types is linked through inter­molecular hy­droxy–ketone O—H⋯O inter­actions, forming one-dimensional chains extending along [010], whereas the other mol­ecule type shows no associations.
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spelling pubmed-33940632012-07-13 Ethyl (E)-3-hy­droxy-2-{N-[2-(thio­phen-2-yl)ethen­yl]carbamo­yl}but-2-enoate Liu, Bao-Shuo Zhao, Sheng-Yin Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(13)H(15)NO(4)S, there are two independent but conformationally similar mol­ecules in the asymmetric unit, both having an E conformation of the side-chain C=C group. Intra­molecular N—H⋯O and O—H⋯O hydrogen-bonding inter­actions are present in both molecules. In the crystal, one of the mol­ecule types is linked through inter­molecular hy­droxy–ketone O—H⋯O inter­actions, forming one-dimensional chains extending along [010], whereas the other mol­ecule type shows no associations. International Union of Crystallography 2012-06-30 /pmc/articles/PMC3394063/ /pubmed/22798928 http://dx.doi.org/10.1107/S1600536812028176 Text en © Liu and Zhao 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Liu, Bao-Shuo
Zhao, Sheng-Yin
Ethyl (E)-3-hy­droxy-2-{N-[2-(thio­phen-2-yl)ethen­yl]carbamo­yl}but-2-enoate
title Ethyl (E)-3-hy­droxy-2-{N-[2-(thio­phen-2-yl)ethen­yl]carbamo­yl}but-2-enoate
title_full Ethyl (E)-3-hy­droxy-2-{N-[2-(thio­phen-2-yl)ethen­yl]carbamo­yl}but-2-enoate
title_fullStr Ethyl (E)-3-hy­droxy-2-{N-[2-(thio­phen-2-yl)ethen­yl]carbamo­yl}but-2-enoate
title_full_unstemmed Ethyl (E)-3-hy­droxy-2-{N-[2-(thio­phen-2-yl)ethen­yl]carbamo­yl}but-2-enoate
title_short Ethyl (E)-3-hy­droxy-2-{N-[2-(thio­phen-2-yl)ethen­yl]carbamo­yl}but-2-enoate
title_sort ethyl (e)-3-hy­droxy-2-{n-[2-(thio­phen-2-yl)ethen­yl]carbamo­yl}but-2-enoate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3394063/
https://www.ncbi.nlm.nih.gov/pubmed/22798928
http://dx.doi.org/10.1107/S1600536812028176
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