Cargando…

4-Nitro-N-[(E)-thio­phen-2-yl­methyl­idene]aniline

In the title compound, C(11)H(8)N(2)O(2)S, there is a twist in the mol­ecule, with the dihedral angle between the five- and six-membered rings being 31.77 (9)°. The nitro group is slightly twisted out of the plane of the benzene ring to which it is attached [O—N—C—C torsion angle = 9.0 (3)°]. The S...

Descripción completa

Detalles Bibliográficos
Autores principales: Asiri, Abdullah M., Faidallah, Hassan M., Ng, Seik Weng, Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3394067/
https://www.ncbi.nlm.nih.gov/pubmed/22798932
http://dx.doi.org/10.1107/S1600536812028346
_version_ 1782237815674765312
author Asiri, Abdullah M.
Faidallah, Hassan M.
Ng, Seik Weng
Tiekink, Edward R. T.
author_facet Asiri, Abdullah M.
Faidallah, Hassan M.
Ng, Seik Weng
Tiekink, Edward R. T.
author_sort Asiri, Abdullah M.
collection PubMed
description In the title compound, C(11)H(8)N(2)O(2)S, there is a twist in the mol­ecule, with the dihedral angle between the five- and six-membered rings being 31.77 (9)°. The nitro group is slightly twisted out of the plane of the benzene ring to which it is attached [O—N—C—C torsion angle = 9.0 (3)°]. The S and N atoms are syn. In the crystal, supra­molecular layers parallel to (-204) are formed by C—H⋯O and C—H⋯N inter­actions. These layers are connected into a three-dimensional architecture by π–π inter­actions occurring between centrosymmetrically related benzene rings [centroid–centroid distance = 3.6020 (11) Å].
format Online
Article
Text
id pubmed-3394067
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-33940672012-07-13 4-Nitro-N-[(E)-thio­phen-2-yl­methyl­idene]aniline Asiri, Abdullah M. Faidallah, Hassan M. Ng, Seik Weng Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(11)H(8)N(2)O(2)S, there is a twist in the mol­ecule, with the dihedral angle between the five- and six-membered rings being 31.77 (9)°. The nitro group is slightly twisted out of the plane of the benzene ring to which it is attached [O—N—C—C torsion angle = 9.0 (3)°]. The S and N atoms are syn. In the crystal, supra­molecular layers parallel to (-204) are formed by C—H⋯O and C—H⋯N inter­actions. These layers are connected into a three-dimensional architecture by π–π inter­actions occurring between centrosymmetrically related benzene rings [centroid–centroid distance = 3.6020 (11) Å]. International Union of Crystallography 2012-06-30 /pmc/articles/PMC3394067/ /pubmed/22798932 http://dx.doi.org/10.1107/S1600536812028346 Text en © Asiri et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Asiri, Abdullah M.
Faidallah, Hassan M.
Ng, Seik Weng
Tiekink, Edward R. T.
4-Nitro-N-[(E)-thio­phen-2-yl­methyl­idene]aniline
title 4-Nitro-N-[(E)-thio­phen-2-yl­methyl­idene]aniline
title_full 4-Nitro-N-[(E)-thio­phen-2-yl­methyl­idene]aniline
title_fullStr 4-Nitro-N-[(E)-thio­phen-2-yl­methyl­idene]aniline
title_full_unstemmed 4-Nitro-N-[(E)-thio­phen-2-yl­methyl­idene]aniline
title_short 4-Nitro-N-[(E)-thio­phen-2-yl­methyl­idene]aniline
title_sort 4-nitro-n-[(e)-thio­phen-2-yl­methyl­idene]aniline
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3394067/
https://www.ncbi.nlm.nih.gov/pubmed/22798932
http://dx.doi.org/10.1107/S1600536812028346
work_keys_str_mv AT asiriabdullahm 4nitronethiophen2ylmethylideneaniline
AT faidallahhassanm 4nitronethiophen2ylmethylideneaniline
AT ngseikweng 4nitronethiophen2ylmethylideneaniline
AT tiekinkedwardrt 4nitronethiophen2ylmethylideneaniline