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4-Nitro-N-[(E)-thiophen-2-ylmethylidene]aniline
In the title compound, C(11)H(8)N(2)O(2)S, there is a twist in the molecule, with the dihedral angle between the five- and six-membered rings being 31.77 (9)°. The nitro group is slightly twisted out of the plane of the benzene ring to which it is attached [O—N—C—C torsion angle = 9.0 (3)°]. The S...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3394067/ https://www.ncbi.nlm.nih.gov/pubmed/22798932 http://dx.doi.org/10.1107/S1600536812028346 |
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author | Asiri, Abdullah M. Faidallah, Hassan M. Ng, Seik Weng Tiekink, Edward R. T. |
author_facet | Asiri, Abdullah M. Faidallah, Hassan M. Ng, Seik Weng Tiekink, Edward R. T. |
author_sort | Asiri, Abdullah M. |
collection | PubMed |
description | In the title compound, C(11)H(8)N(2)O(2)S, there is a twist in the molecule, with the dihedral angle between the five- and six-membered rings being 31.77 (9)°. The nitro group is slightly twisted out of the plane of the benzene ring to which it is attached [O—N—C—C torsion angle = 9.0 (3)°]. The S and N atoms are syn. In the crystal, supramolecular layers parallel to (-204) are formed by C—H⋯O and C—H⋯N interactions. These layers are connected into a three-dimensional architecture by π–π interactions occurring between centrosymmetrically related benzene rings [centroid–centroid distance = 3.6020 (11) Å]. |
format | Online Article Text |
id | pubmed-3394067 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33940672012-07-13 4-Nitro-N-[(E)-thiophen-2-ylmethylidene]aniline Asiri, Abdullah M. Faidallah, Hassan M. Ng, Seik Weng Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(11)H(8)N(2)O(2)S, there is a twist in the molecule, with the dihedral angle between the five- and six-membered rings being 31.77 (9)°. The nitro group is slightly twisted out of the plane of the benzene ring to which it is attached [O—N—C—C torsion angle = 9.0 (3)°]. The S and N atoms are syn. In the crystal, supramolecular layers parallel to (-204) are formed by C—H⋯O and C—H⋯N interactions. These layers are connected into a three-dimensional architecture by π–π interactions occurring between centrosymmetrically related benzene rings [centroid–centroid distance = 3.6020 (11) Å]. International Union of Crystallography 2012-06-30 /pmc/articles/PMC3394067/ /pubmed/22798932 http://dx.doi.org/10.1107/S1600536812028346 Text en © Asiri et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Asiri, Abdullah M. Faidallah, Hassan M. Ng, Seik Weng Tiekink, Edward R. T. 4-Nitro-N-[(E)-thiophen-2-ylmethylidene]aniline |
title | 4-Nitro-N-[(E)-thiophen-2-ylmethylidene]aniline |
title_full | 4-Nitro-N-[(E)-thiophen-2-ylmethylidene]aniline |
title_fullStr | 4-Nitro-N-[(E)-thiophen-2-ylmethylidene]aniline |
title_full_unstemmed | 4-Nitro-N-[(E)-thiophen-2-ylmethylidene]aniline |
title_short | 4-Nitro-N-[(E)-thiophen-2-ylmethylidene]aniline |
title_sort | 4-nitro-n-[(e)-thiophen-2-ylmethylidene]aniline |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3394067/ https://www.ncbi.nlm.nih.gov/pubmed/22798932 http://dx.doi.org/10.1107/S1600536812028346 |
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