2-[(E)-({3-[(E)-(2-Hy­droxy­benzyl­idene)amino­meth­yl]-1,4-dioxaspiro­[4.5]decan-2-yl}meth­yl)imino­meth­yl]phenol

In the title compound, C(24)H(28)N(2)O(4), the dioxalane ring has an envelope conformation. The cyclo­hexane ring adopts a chair conformation. The dihedral angle between the benzene rings is 72.5 (3)°. The mol­ecular conformation is stabilized by two intra­molecular O—H⋯N hydrogen-bonding inter­acti...

Descripción completa

Detalles Bibliográficos
Autores principales: Jiang, Yan, Wang, Lili, Bian, Jing, Du, Xiaoying, Sun, Xiaoqiang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3394072/
https://www.ncbi.nlm.nih.gov/pubmed/22798937
http://dx.doi.org/10.1107/S1600536812029182
_version_ 1782237816858607616
author Jiang, Yan
Wang, Lili
Bian, Jing
Du, Xiaoying
Sun, Xiaoqiang
author_facet Jiang, Yan
Wang, Lili
Bian, Jing
Du, Xiaoying
Sun, Xiaoqiang
author_sort Jiang, Yan
collection PubMed
description In the title compound, C(24)H(28)N(2)O(4), the dioxalane ring has an envelope conformation. The cyclo­hexane ring adopts a chair conformation. The dihedral angle between the benzene rings is 72.5 (3)°. The mol­ecular conformation is stabilized by two intra­molecular O—H⋯N hydrogen-bonding inter­actions with an S(6) graph-set motif. The crystal structure is stabilized by van der Waals inter­actions.
format Online
Article
Text
id pubmed-3394072
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-33940722012-07-13 2-[(E)-({3-[(E)-(2-Hy­droxy­benzyl­idene)amino­meth­yl]-1,4-dioxaspiro­[4.5]decan-2-yl}meth­yl)imino­meth­yl]phenol Jiang, Yan Wang, Lili Bian, Jing Du, Xiaoying Sun, Xiaoqiang Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(24)H(28)N(2)O(4), the dioxalane ring has an envelope conformation. The cyclo­hexane ring adopts a chair conformation. The dihedral angle between the benzene rings is 72.5 (3)°. The mol­ecular conformation is stabilized by two intra­molecular O—H⋯N hydrogen-bonding inter­actions with an S(6) graph-set motif. The crystal structure is stabilized by van der Waals inter­actions. International Union of Crystallography 2012-06-30 /pmc/articles/PMC3394072/ /pubmed/22798937 http://dx.doi.org/10.1107/S1600536812029182 Text en © Jiang et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Jiang, Yan
Wang, Lili
Bian, Jing
Du, Xiaoying
Sun, Xiaoqiang
2-[(E)-({3-[(E)-(2-Hy­droxy­benzyl­idene)amino­meth­yl]-1,4-dioxaspiro­[4.5]decan-2-yl}meth­yl)imino­meth­yl]phenol
title 2-[(E)-({3-[(E)-(2-Hy­droxy­benzyl­idene)amino­meth­yl]-1,4-dioxaspiro­[4.5]decan-2-yl}meth­yl)imino­meth­yl]phenol
title_full 2-[(E)-({3-[(E)-(2-Hy­droxy­benzyl­idene)amino­meth­yl]-1,4-dioxaspiro­[4.5]decan-2-yl}meth­yl)imino­meth­yl]phenol
title_fullStr 2-[(E)-({3-[(E)-(2-Hy­droxy­benzyl­idene)amino­meth­yl]-1,4-dioxaspiro­[4.5]decan-2-yl}meth­yl)imino­meth­yl]phenol
title_full_unstemmed 2-[(E)-({3-[(E)-(2-Hy­droxy­benzyl­idene)amino­meth­yl]-1,4-dioxaspiro­[4.5]decan-2-yl}meth­yl)imino­meth­yl]phenol
title_short 2-[(E)-({3-[(E)-(2-Hy­droxy­benzyl­idene)amino­meth­yl]-1,4-dioxaspiro­[4.5]decan-2-yl}meth­yl)imino­meth­yl]phenol
title_sort 2-[(e)-({3-[(e)-(2-hy­droxy­benzyl­idene)amino­meth­yl]-1,4-dioxaspiro­[4.5]decan-2-yl}meth­yl)imino­meth­yl]phenol
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3394072/
https://www.ncbi.nlm.nih.gov/pubmed/22798937
http://dx.doi.org/10.1107/S1600536812029182
work_keys_str_mv AT jiangyan 2e3e2hydroxybenzylideneaminomethyl14dioxaspiro45decan2ylmethyliminomethylphenol
AT wanglili 2e3e2hydroxybenzylideneaminomethyl14dioxaspiro45decan2ylmethyliminomethylphenol
AT bianjing 2e3e2hydroxybenzylideneaminomethyl14dioxaspiro45decan2ylmethyliminomethylphenol
AT duxiaoying 2e3e2hydroxybenzylideneaminomethyl14dioxaspiro45decan2ylmethyliminomethylphenol
AT sunxiaoqiang 2e3e2hydroxybenzylideneaminomethyl14dioxaspiro45decan2ylmethyliminomethylphenol

Ejemplares similares