1-(2-Chloro­benz­yl)-3-methyl-2,6-diphenyl­piperidine

In the title compound, C(25)H(26)ClN, the piperidine ring has a chair conformation with all ring substituents in equatorial positions. The dihedral angle formed between the chloro­benzene ring and the flanking phenyl rings are 74.91 (18) and 47.86 (17)°. The chloro substituent is anti to the piperid...

Descripción completa

Detalles Bibliográficos
Autores principales: Ramalingan, Chennan, Ng, Seik Weng, Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3394076/
https://www.ncbi.nlm.nih.gov/pubmed/22798941
http://dx.doi.org/10.1107/S1600536812029200
_version_ 1782237817755140096
author Ramalingan, Chennan
Ng, Seik Weng
Tiekink, Edward R. T.
author_facet Ramalingan, Chennan
Ng, Seik Weng
Tiekink, Edward R. T.
author_sort Ramalingan, Chennan
collection PubMed
description In the title compound, C(25)H(26)ClN, the piperidine ring has a chair conformation with all ring substituents in equatorial positions. The dihedral angle formed between the chloro­benzene ring and the flanking phenyl rings are 74.91 (18) and 47.86 (17)°. The chloro substituent is anti to the piperidine N atom. In the crystal, centrosymmetrically related mol­ecules aggregate via π–π inter­actions occurring between chloro­benzene rings [centroid–centroid distance = 3.778 (2) Å] and these are linked into linear supra­molecular chains along the a axis by C—H⋯π inter­actions occurring between the phenyl rings.
format Online
Article
Text
id pubmed-3394076
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-33940762012-07-13 1-(2-Chloro­benz­yl)-3-methyl-2,6-diphenyl­piperidine Ramalingan, Chennan Ng, Seik Weng Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(25)H(26)ClN, the piperidine ring has a chair conformation with all ring substituents in equatorial positions. The dihedral angle formed between the chloro­benzene ring and the flanking phenyl rings are 74.91 (18) and 47.86 (17)°. The chloro substituent is anti to the piperidine N atom. In the crystal, centrosymmetrically related mol­ecules aggregate via π–π inter­actions occurring between chloro­benzene rings [centroid–centroid distance = 3.778 (2) Å] and these are linked into linear supra­molecular chains along the a axis by C—H⋯π inter­actions occurring between the phenyl rings. International Union of Crystallography 2012-06-30 /pmc/articles/PMC3394076/ /pubmed/22798941 http://dx.doi.org/10.1107/S1600536812029200 Text en © Ramalingan et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ramalingan, Chennan
Ng, Seik Weng
Tiekink, Edward R. T.
1-(2-Chloro­benz­yl)-3-methyl-2,6-diphenyl­piperidine
title 1-(2-Chloro­benz­yl)-3-methyl-2,6-diphenyl­piperidine
title_full 1-(2-Chloro­benz­yl)-3-methyl-2,6-diphenyl­piperidine
title_fullStr 1-(2-Chloro­benz­yl)-3-methyl-2,6-diphenyl­piperidine
title_full_unstemmed 1-(2-Chloro­benz­yl)-3-methyl-2,6-diphenyl­piperidine
title_short 1-(2-Chloro­benz­yl)-3-methyl-2,6-diphenyl­piperidine
title_sort 1-(2-chloro­benz­yl)-3-methyl-2,6-diphenyl­piperidine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3394076/
https://www.ncbi.nlm.nih.gov/pubmed/22798941
http://dx.doi.org/10.1107/S1600536812029200
work_keys_str_mv AT ramalinganchennan 12chlorobenzyl3methyl26diphenylpiperidine
AT ngseikweng 12chlorobenzyl3methyl26diphenylpiperidine
AT tiekinkedwardrt 12chlorobenzyl3methyl26diphenylpiperidine

Ejemplares similares