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1-(2-Chloro­benz­yl)-3,5-dimethyl-2,6-diphenyl­piperidine

Two independent mol­ecules (A and B) comprise the asymmetric unit of the title compound, C(26)H(28)ClN, with the inverted form of B almost superimposable upon A. Each piperidine ring has a chair conformation and the chloro substituent is anti to the piperidine N atom. Each of two aromatic rings, the...

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Detalles Bibliográficos
Autores principales: Ramalingan, Chennan, Ng, Seik Weng, Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3394077/
https://www.ncbi.nlm.nih.gov/pubmed/22798942
http://dx.doi.org/10.1107/S1600536812029212
Descripción
Sumario:Two independent mol­ecules (A and B) comprise the asymmetric unit of the title compound, C(26)H(28)ClN, with the inverted form of B almost superimposable upon A. Each piperidine ring has a chair conformation and the chloro substituent is anti to the piperidine N atom. Each of two aromatic rings, the benzyl residue and one methyl group substituents occupies an equatorial position, and the second methyl substituent occupies an axial position. The dihedral angle formed between the chloro­benzene ring and the flanking phenyl rings in mol­ecule A are 84.24 (9) and 24.85 (8)°; the equivalent angles for mol­ecule B are 79.97 (9) and 28.33 (9)°. In the crystal, the A and B mol­ecules are connected by C—H⋯Cl and C—H⋯π inter­actions, forming a supra­molecular chain along [101].