N′-[(E)-4-Chloro­benzyl­idene]pyridine-4-carbohydrazide monohydrate

The asymmetric unit of the title compound, C(13)H(10)ClN(3)O·H(2)O, consists of two crystallographically independent Schiff base mol­ecules which exist in an E conformation with respect to the C=N double bond, and two independent water mol­ecules. In the crystal, the Schiff base and water mol­ecules...

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Autores principales: Fun, Hoong-Kun, Loh, Wan-Sin, Shetty, Divya N., Narayana, B., Sarojini, B. K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3394078/
https://www.ncbi.nlm.nih.gov/pubmed/22798943
http://dx.doi.org/10.1107/S1600536812029121
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author Fun, Hoong-Kun
Loh, Wan-Sin
Shetty, Divya N.
Narayana, B.
Sarojini, B. K.
author_facet Fun, Hoong-Kun
Loh, Wan-Sin
Shetty, Divya N.
Narayana, B.
Sarojini, B. K.
author_sort Fun, Hoong-Kun
collection PubMed
description The asymmetric unit of the title compound, C(13)H(10)ClN(3)O·H(2)O, consists of two crystallographically independent Schiff base mol­ecules which exist in an E conformation with respect to the C=N double bond, and two independent water mol­ecules. In the crystal, the Schiff base and water mol­ecules are linked into a three-dimensional network via N—H⋯O, O—H⋯N, O—H⋯O and C—H⋯O hydrogen bonds. The crystal studied was a pseudo-merohedral twin with twin law (101 0-10 00-1) and a component ratio of 0.792 (2):0.208 (2).
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spelling pubmed-33940782012-07-13 N′-[(E)-4-Chloro­benzyl­idene]pyridine-4-carbohydrazide monohydrate Fun, Hoong-Kun Loh, Wan-Sin Shetty, Divya N. Narayana, B. Sarojini, B. K. Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(13)H(10)ClN(3)O·H(2)O, consists of two crystallographically independent Schiff base mol­ecules which exist in an E conformation with respect to the C=N double bond, and two independent water mol­ecules. In the crystal, the Schiff base and water mol­ecules are linked into a three-dimensional network via N—H⋯O, O—H⋯N, O—H⋯O and C—H⋯O hydrogen bonds. The crystal studied was a pseudo-merohedral twin with twin law (101 0-10 00-1) and a component ratio of 0.792 (2):0.208 (2). International Union of Crystallography 2012-06-30 /pmc/articles/PMC3394078/ /pubmed/22798943 http://dx.doi.org/10.1107/S1600536812029121 Text en © Fun et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fun, Hoong-Kun
Loh, Wan-Sin
Shetty, Divya N.
Narayana, B.
Sarojini, B. K.
N′-[(E)-4-Chloro­benzyl­idene]pyridine-4-carbohydrazide monohydrate
title N′-[(E)-4-Chloro­benzyl­idene]pyridine-4-carbohydrazide monohydrate
title_full N′-[(E)-4-Chloro­benzyl­idene]pyridine-4-carbohydrazide monohydrate
title_fullStr N′-[(E)-4-Chloro­benzyl­idene]pyridine-4-carbohydrazide monohydrate
title_full_unstemmed N′-[(E)-4-Chloro­benzyl­idene]pyridine-4-carbohydrazide monohydrate
title_short N′-[(E)-4-Chloro­benzyl­idene]pyridine-4-carbohydrazide monohydrate
title_sort n′-[(e)-4-chloro­benzyl­idene]pyridine-4-carbohydrazide monohydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3394078/
https://www.ncbi.nlm.nih.gov/pubmed/22798943
http://dx.doi.org/10.1107/S1600536812029121
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