Vibrational Stark Effect of the Electric-Field Reporter 4-Mercaptobenzonitrile as a Tool for Investigating Electrostatics at Electrode/SAM/Solution Interfaces

4-mercaptobenzonitrile (MBN) in self-assembled monolayers (SAMs) on Au and Ag electrodes was studied by surface enhanced infrared absorption and Raman spectroscopy, to correlate the nitrile stretching frequency with the local electric field exploiting the vibrational Stark effect (VSE). Using MBN SA...

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Detalles Bibliográficos
Autores principales: Schkolnik, Gal, Salewski, Johannes, Millo, Diego, Zebger, Ingo, Franzen, Stefan, Hildebrandt, Peter
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Molecular Diversity Preservation International (MDPI) 2012
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3397537/
https://www.ncbi.nlm.nih.gov/pubmed/22837705
http://dx.doi.org/10.3390/ijms13067466

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