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Synthesis of Block Copolymers of Varying Architecture Through Suppression of Transesterification during Coordinated Anionic Ring Opening Polymerization

Well-defined di- and triblock copolymers consisting of ε -caprolactone (CL), L-lactide (LA), and trimethylene carbonate (TMC) were synthesized via “PLA first route” in coordinated anionic ring opening polymerization/copolymerization (CAROP) with tin (II) octoate as catalyst. The desired block struct...

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Detalles Bibliográficos
Autores principales: Lipik, Vitali T., Abadie, Marc J. M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Hindawi Publishing Corporation 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3398607/
https://www.ncbi.nlm.nih.gov/pubmed/22844286
http://dx.doi.org/10.1155/2012/390947