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Switchable molecular magnets

Various molecular magnetic compounds whose magnetic properties can be controlled by external stimuli have been developed, including electrochemically, photochemically, and chemically tunable bulk magnets as well as a phototunable antiferromagnetic phase of single chain magnet. In addition, we presen...

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Detalles Bibliográficos
Autor principal: SATO, Osamu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Japan Academy 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3410140/
https://www.ncbi.nlm.nih.gov/pubmed/22728438
http://dx.doi.org/10.2183/pjab.88.213
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author SATO, Osamu
author_facet SATO, Osamu
author_sort SATO, Osamu
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description Various molecular magnetic compounds whose magnetic properties can be controlled by external stimuli have been developed, including electrochemically, photochemically, and chemically tunable bulk magnets as well as a phototunable antiferromagnetic phase of single chain magnet. In addition, we present tunable paramagnetic mononuclear complexes ranging from spin crossover complexes and valence tautomeric complexes to Co complexes in which orbital angular momentum can be switched. Furthermore, we recently developed several switchable clusters and one-dimensional coordination polymers. The switching of magnetic properties can be achieved by modulating metals, ligands, and molecules/ions in the second sphere of the complexes.
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spelling pubmed-34101402012-08-20 Switchable molecular magnets SATO, Osamu Proc Jpn Acad Ser B Phys Biol Sci Review Various molecular magnetic compounds whose magnetic properties can be controlled by external stimuli have been developed, including electrochemically, photochemically, and chemically tunable bulk magnets as well as a phototunable antiferromagnetic phase of single chain magnet. In addition, we present tunable paramagnetic mononuclear complexes ranging from spin crossover complexes and valence tautomeric complexes to Co complexes in which orbital angular momentum can be switched. Furthermore, we recently developed several switchable clusters and one-dimensional coordination polymers. The switching of magnetic properties can be achieved by modulating metals, ligands, and molecules/ions in the second sphere of the complexes. The Japan Academy 2012-06-11 /pmc/articles/PMC3410140/ /pubmed/22728438 http://dx.doi.org/10.2183/pjab.88.213 Text en © 2012 The Japan Academy This is an open access article distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
spellingShingle Review
SATO, Osamu
Switchable molecular magnets
title Switchable molecular magnets
title_full Switchable molecular magnets
title_fullStr Switchable molecular magnets
title_full_unstemmed Switchable molecular magnets
title_short Switchable molecular magnets
title_sort switchable molecular magnets
topic Review
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3410140/
https://www.ncbi.nlm.nih.gov/pubmed/22728438
http://dx.doi.org/10.2183/pjab.88.213
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