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Dilead(II) trimanganese(II) bis(hydrogenphosphate) bis(phosphate)

The title compound, Pb(2)Mn(3)(HPO(4))(2)(PO(4))(2), was synthesized by a hydro­thermal method. All atoms are in general positions except for one Mn atom which is located on an inversion center. The framework of the structure is built up from PO(4) tetra­hedra and two types of MnO(6) octa­hedra, one...

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Autores principales: Assani, Abderrazzak, Saadi, Mohamed, Zriouil, Mohammed, El Ammari, Lahcen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414095/
https://www.ncbi.nlm.nih.gov/pubmed/22904702
http://dx.doi.org/10.1107/S1600536812033259
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author Assani, Abderrazzak
Saadi, Mohamed
Zriouil, Mohammed
El Ammari, Lahcen
author_facet Assani, Abderrazzak
Saadi, Mohamed
Zriouil, Mohammed
El Ammari, Lahcen
author_sort Assani, Abderrazzak
collection PubMed
description The title compound, Pb(2)Mn(3)(HPO(4))(2)(PO(4))(2), was synthesized by a hydro­thermal method. All atoms are in general positions except for one Mn atom which is located on an inversion center. The framework of the structure is built up from PO(4) tetra­hedra and two types of MnO(6) octa­hedra, one almost ideal and the other very distorted with one very long Mn—O bond [2.610 (4) Å compared an average of 2.161 Å for the other bonds]. The centrosymetric octa­hedron is linked to two distorted MnO(6) octa­hedra by an edge common, forming infinite zigzag Mn(3)O(14) chains running along the b axis. Adjacent chains are linked by PO(4) and PO(3)(OH) tetra­hedra through vertices or by edge sharing, forming sheets perpendicular to [100]. The Pb(2+) cations are sandwiched between the layers and ensure the cohesion of the crystal structure. O—H⋯O hydrogen bonding between the layers is also observed.
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spelling pubmed-34140952012-08-17 Dilead(II) trimanganese(II) bis(hydrogenphosphate) bis(phosphate) Assani, Abderrazzak Saadi, Mohamed Zriouil, Mohammed El Ammari, Lahcen Acta Crystallogr Sect E Struct Rep Online Inorganic Papers The title compound, Pb(2)Mn(3)(HPO(4))(2)(PO(4))(2), was synthesized by a hydro­thermal method. All atoms are in general positions except for one Mn atom which is located on an inversion center. The framework of the structure is built up from PO(4) tetra­hedra and two types of MnO(6) octa­hedra, one almost ideal and the other very distorted with one very long Mn—O bond [2.610 (4) Å compared an average of 2.161 Å for the other bonds]. The centrosymetric octa­hedron is linked to two distorted MnO(6) octa­hedra by an edge common, forming infinite zigzag Mn(3)O(14) chains running along the b axis. Adjacent chains are linked by PO(4) and PO(3)(OH) tetra­hedra through vertices or by edge sharing, forming sheets perpendicular to [100]. The Pb(2+) cations are sandwiched between the layers and ensure the cohesion of the crystal structure. O—H⋯O hydrogen bonding between the layers is also observed. International Union of Crystallography 2012-07-28 /pmc/articles/PMC3414095/ /pubmed/22904702 http://dx.doi.org/10.1107/S1600536812033259 Text en © Assani et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Inorganic Papers
Assani, Abderrazzak
Saadi, Mohamed
Zriouil, Mohammed
El Ammari, Lahcen
Dilead(II) trimanganese(II) bis(hydrogenphosphate) bis(phosphate)
title Dilead(II) trimanganese(II) bis(hydrogenphosphate) bis(phosphate)
title_full Dilead(II) trimanganese(II) bis(hydrogenphosphate) bis(phosphate)
title_fullStr Dilead(II) trimanganese(II) bis(hydrogenphosphate) bis(phosphate)
title_full_unstemmed Dilead(II) trimanganese(II) bis(hydrogenphosphate) bis(phosphate)
title_short Dilead(II) trimanganese(II) bis(hydrogenphosphate) bis(phosphate)
title_sort dilead(ii) trimanganese(ii) bis(hydrogenphosphate) bis(phosphate)
topic Inorganic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414095/
https://www.ncbi.nlm.nih.gov/pubmed/22904702
http://dx.doi.org/10.1107/S1600536812033259
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