Poly[tetra­aqua­bis­(μ(4)-thio­phene-2,5-dicarboxyl­ato)(μ(2)-thio­phene-2,5-dicarboxyl­ato)dieuropium(III)]

The three-dimensional coordination polymer, [Eu(2)(C(6)H(2)O(4)S)(3)(H(2)O)(4)](n), has been synthesized under hydro­thermal conditions. The asymmetric unit comprises one Eu(3+) cation, two aqua ligands and one and a half thiophene-2,5-dicarboxylate anions (the half-anion being completed by a twofol...

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Detalles Bibliográficos
Autores principales: Du, Xi-Gang, Zhang, Jun, Li, Jia-Jia
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414099/
https://www.ncbi.nlm.nih.gov/pubmed/22904706
http://dx.doi.org/10.1107/S1600536812029546
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author Du, Xi-Gang
Zhang, Jun
Li, Jia-Jia
author_facet Du, Xi-Gang
Zhang, Jun
Li, Jia-Jia
author_sort Du, Xi-Gang
collection PubMed
description The three-dimensional coordination polymer, [Eu(2)(C(6)H(2)O(4)S)(3)(H(2)O)(4)](n), has been synthesized under hydro­thermal conditions. The asymmetric unit comprises one Eu(3+) cation, two aqua ligands and one and a half thiophene-2,5-dicarboxylate anions (the half-anion being completed by a twofold rotation axis). The Eu(3+) cation is eight-coordinated in a distorted dodeca­hedral geometry. The crystal structure features O—H⋯O hydrogen bonds.
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spelling pubmed-34140992012-08-17 Poly[tetra­aqua­bis­(μ(4)-thio­phene-2,5-dicarboxyl­ato)(μ(2)-thio­phene-2,5-dicarboxyl­ato)dieuropium(III)] Du, Xi-Gang Zhang, Jun Li, Jia-Jia Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The three-dimensional coordination polymer, [Eu(2)(C(6)H(2)O(4)S)(3)(H(2)O)(4)](n), has been synthesized under hydro­thermal conditions. The asymmetric unit comprises one Eu(3+) cation, two aqua ligands and one and a half thiophene-2,5-dicarboxylate anions (the half-anion being completed by a twofold rotation axis). The Eu(3+) cation is eight-coordinated in a distorted dodeca­hedral geometry. The crystal structure features O—H⋯O hydrogen bonds. International Union of Crystallography 2012-07-04 /pmc/articles/PMC3414099/ /pubmed/22904706 http://dx.doi.org/10.1107/S1600536812029546 Text en © Du et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Du, Xi-Gang
Zhang, Jun
Li, Jia-Jia
Poly[tetra­aqua­bis­(μ(4)-thio­phene-2,5-dicarboxyl­ato)(μ(2)-thio­phene-2,5-dicarboxyl­ato)dieuropium(III)]
title Poly[tetra­aqua­bis­(μ(4)-thio­phene-2,5-dicarboxyl­ato)(μ(2)-thio­phene-2,5-dicarboxyl­ato)dieuropium(III)]
title_full Poly[tetra­aqua­bis­(μ(4)-thio­phene-2,5-dicarboxyl­ato)(μ(2)-thio­phene-2,5-dicarboxyl­ato)dieuropium(III)]
title_fullStr Poly[tetra­aqua­bis­(μ(4)-thio­phene-2,5-dicarboxyl­ato)(μ(2)-thio­phene-2,5-dicarboxyl­ato)dieuropium(III)]
title_full_unstemmed Poly[tetra­aqua­bis­(μ(4)-thio­phene-2,5-dicarboxyl­ato)(μ(2)-thio­phene-2,5-dicarboxyl­ato)dieuropium(III)]
title_short Poly[tetra­aqua­bis­(μ(4)-thio­phene-2,5-dicarboxyl­ato)(μ(2)-thio­phene-2,5-dicarboxyl­ato)dieuropium(III)]
title_sort poly[tetra­aqua­bis­(μ(4)-thio­phene-2,5-dicarboxyl­ato)(μ(2)-thio­phene-2,5-dicarboxyl­ato)dieuropium(iii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414099/
https://www.ncbi.nlm.nih.gov/pubmed/22904706
http://dx.doi.org/10.1107/S1600536812029546
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AT lijiajia polytetraaquabism4thiophene25dicarboxylatom2thiophene25dicarboxylatodieuropiumiii

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