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Potassium morpholine-4-carbodithioate monohydrate
In the ionic title compound, K(+)·C(5)H(8)NOS(2) (−)·H(2)O, the morpholine ring of the morpholine-4-carbodithioate anion has a chair conformation. The potassium cation is coordinated by four S and four O atoms in a bipyramidal reversed geometry. In the crystal, the three components are linked, gene...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414100/ https://www.ncbi.nlm.nih.gov/pubmed/22904707 http://dx.doi.org/10.1107/S1600536812029613 |
Sumario: | In the ionic title compound, K(+)·C(5)H(8)NOS(2) (−)·H(2)O, the morpholine ring of the morpholine-4-carbodithioate anion has a chair conformation. The potassium cation is coordinated by four S and four O atoms in a bipyramidal reversed geometry. In the crystal, the three components are linked, generating infinite two-dimensional networks that lie parallel to the bc plane. These layers are linked via O—H⋯S hydrogen bonds, forming a three-dimensional structure. |
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