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Potassium morpholine-4-carbodithio­ate monohydrate

In the ionic title compound, K(+)·C(5)H(8)NOS(2) (−)·H(2)O, the morpholine ring of the morpholine-4-carbodithio­ate anion has a chair conformation. The potassium cation is coordinated by four S and four O atoms in a bipyramidal reversed geometry. In the crystal, the three components are linked, gene...

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Detalles Bibliográficos
Autor principal: Mafud, Ana C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414100/
https://www.ncbi.nlm.nih.gov/pubmed/22904707
http://dx.doi.org/10.1107/S1600536812029613
Descripción
Sumario:In the ionic title compound, K(+)·C(5)H(8)NOS(2) (−)·H(2)O, the morpholine ring of the morpholine-4-carbodithio­ate anion has a chair conformation. The potassium cation is coordinated by four S and four O atoms in a bipyramidal reversed geometry. In the crystal, the three components are linked, generating infinite two-dimensional networks that lie parallel to the bc plane. These layers are linked via O—H⋯S hydrogen bonds, forming a three-dimensional structure.