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Potassium morpholine-4-carbodithioate monohydrate
In the ionic title compound, K(+)·C(5)H(8)NOS(2) (−)·H(2)O, the morpholine ring of the morpholine-4-carbodithioate anion has a chair conformation. The potassium cation is coordinated by four S and four O atoms in a bipyramidal reversed geometry. In the crystal, the three components are linked, gene...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2012
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414100/ https://www.ncbi.nlm.nih.gov/pubmed/22904707 http://dx.doi.org/10.1107/S1600536812029613 |
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author | Mafud, Ana C. |
author_facet | Mafud, Ana C. |
author_sort | Mafud, Ana C. |
collection | PubMed |
description | In the ionic title compound, K(+)·C(5)H(8)NOS(2) (−)·H(2)O, the morpholine ring of the morpholine-4-carbodithioate anion has a chair conformation. The potassium cation is coordinated by four S and four O atoms in a bipyramidal reversed geometry. In the crystal, the three components are linked, generating infinite two-dimensional networks that lie parallel to the bc plane. These layers are linked via O—H⋯S hydrogen bonds, forming a three-dimensional structure. |
format | Online Article Text |
id | pubmed-3414100 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-34141002012-08-17 Potassium morpholine-4-carbodithioate monohydrate Mafud, Ana C. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the ionic title compound, K(+)·C(5)H(8)NOS(2) (−)·H(2)O, the morpholine ring of the morpholine-4-carbodithioate anion has a chair conformation. The potassium cation is coordinated by four S and four O atoms in a bipyramidal reversed geometry. In the crystal, the three components are linked, generating infinite two-dimensional networks that lie parallel to the bc plane. These layers are linked via O—H⋯S hydrogen bonds, forming a three-dimensional structure. International Union of Crystallography 2012-07-04 /pmc/articles/PMC3414100/ /pubmed/22904707 http://dx.doi.org/10.1107/S1600536812029613 Text en © Ana C. Mafud 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Mafud, Ana C. Potassium morpholine-4-carbodithioate monohydrate |
title | Potassium morpholine-4-carbodithioate monohydrate |
title_full | Potassium morpholine-4-carbodithioate monohydrate |
title_fullStr | Potassium morpholine-4-carbodithioate monohydrate |
title_full_unstemmed | Potassium morpholine-4-carbodithioate monohydrate |
title_short | Potassium morpholine-4-carbodithioate monohydrate |
title_sort | potassium morpholine-4-carbodithioate monohydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414100/ https://www.ncbi.nlm.nih.gov/pubmed/22904707 http://dx.doi.org/10.1107/S1600536812029613 |
work_keys_str_mv | AT mafudanac potassiummorpholine4carbodithioatemonohydrate |