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Potassium morpholine-4-carbodithio­ate monohydrate

In the ionic title compound, K(+)·C(5)H(8)NOS(2) (−)·H(2)O, the morpholine ring of the morpholine-4-carbodithio­ate anion has a chair conformation. The potassium cation is coordinated by four S and four O atoms in a bipyramidal reversed geometry. In the crystal, the three components are linked, gene...

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Autor principal: Mafud, Ana C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414100/
https://www.ncbi.nlm.nih.gov/pubmed/22904707
http://dx.doi.org/10.1107/S1600536812029613
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author Mafud, Ana C.
author_facet Mafud, Ana C.
author_sort Mafud, Ana C.
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description In the ionic title compound, K(+)·C(5)H(8)NOS(2) (−)·H(2)O, the morpholine ring of the morpholine-4-carbodithio­ate anion has a chair conformation. The potassium cation is coordinated by four S and four O atoms in a bipyramidal reversed geometry. In the crystal, the three components are linked, generating infinite two-dimensional networks that lie parallel to the bc plane. These layers are linked via O—H⋯S hydrogen bonds, forming a three-dimensional structure.
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spelling pubmed-34141002012-08-17 Potassium morpholine-4-carbodithio­ate monohydrate Mafud, Ana C. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the ionic title compound, K(+)·C(5)H(8)NOS(2) (−)·H(2)O, the morpholine ring of the morpholine-4-carbodithio­ate anion has a chair conformation. The potassium cation is coordinated by four S and four O atoms in a bipyramidal reversed geometry. In the crystal, the three components are linked, generating infinite two-dimensional networks that lie parallel to the bc plane. These layers are linked via O—H⋯S hydrogen bonds, forming a three-dimensional structure. International Union of Crystallography 2012-07-04 /pmc/articles/PMC3414100/ /pubmed/22904707 http://dx.doi.org/10.1107/S1600536812029613 Text en © Ana C. Mafud 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Mafud, Ana C.
Potassium morpholine-4-carbodithio­ate monohydrate
title Potassium morpholine-4-carbodithio­ate monohydrate
title_full Potassium morpholine-4-carbodithio­ate monohydrate
title_fullStr Potassium morpholine-4-carbodithio­ate monohydrate
title_full_unstemmed Potassium morpholine-4-carbodithio­ate monohydrate
title_short Potassium morpholine-4-carbodithio­ate monohydrate
title_sort potassium morpholine-4-carbodithio­ate monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414100/
https://www.ncbi.nlm.nih.gov/pubmed/22904707
http://dx.doi.org/10.1107/S1600536812029613
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