trans-Bis(nitrato-κO)bis­(1,10-phenanthroline-κ(2) N,N′)manganese(II)

In the title compound, [Mn(NO(3))(2)(C(12)H(8)N(2))(2)], the Mn(II) atom lies on a twofold rotation axis, and is six-coordinated in a distorted trans-N(4)O(2) octa­hedral environment by four N atoms from two 1,10-phenanthroline ligands and two O atoms from two nitrate anions. The nitrate anion is di...

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Detalles Bibliográficos
Autores principales: Saphu, Watcharin, Chanthee, Songwuit, Chainok, Kittipong, Harding, David J., Pakawatchai, Chaveng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414101/
https://www.ncbi.nlm.nih.gov/pubmed/22904708
http://dx.doi.org/10.1107/S1600536812029364
Descripción
Sumario:In the title compound, [Mn(NO(3))(2)(C(12)H(8)N(2))(2)], the Mn(II) atom lies on a twofold rotation axis, and is six-coordinated in a distorted trans-N(4)O(2) octa­hedral environment by four N atoms from two 1,10-phenanthroline ligands and two O atoms from two nitrate anions. The nitrate anion is disordered about a twofold rotation axis with fixed occupancy factors of 0.5. In the crystal, mol­ecules are linked by weak C—H⋯O hydrogen bonds and π–π stacking inter­actions [centroid–centroid distance = 4.088 (5) Å] into a three-dimensional supra­molecular network.

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