{μ-2-[(3-Amino-2,2-dimethyl­prop­yl)imino­meth­yl]-6-meth­oxy­phenolato-1:2κ(5) O (1),O (6):N,N′,O (1)}{2-[(3-amino-2,2-dimethyl­prop­yl)imino­meth­yl]-6-meth­oxy­phenolato-1κ(3) N,N′,O (1)}-μ-azido-1:2κ(2) N:N-azido-2κN-methanol-2κO-dinickel(II)

Two distinct coordination geometries are found in the binuclear title complex, [Ni(2)(C(13)H(19)N(2)O(2))(2)(N(3))(2)(CH(3)OH)], as one Schiff base ligand is penta­dentate, coordinating via the anti­cipated oxide O, imine N and amine N atoms (as for the second, tridentate, ligand) but the oxide O is...

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Detalles Bibliográficos
Autores principales: Ghaemi, Akbar, Rayati, Saeed, Fayyazi, Kazem, Ng, Seik Weng, Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414102/
https://www.ncbi.nlm.nih.gov/pubmed/22904709
http://dx.doi.org/10.1107/S1600536812029662

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