Aquachloridobis[2-(1,3-thia­zol-4-yl-κN)-1H-benzimidazole-κN (3)]nickel(II) nitrate

In the title compound, [NiCl(C(10)H(7)N(3)S)(2)(H(2)O)]NO(3), the Ni(II) ion is coordinated by four N atoms from two chelating 2-(1,3-thia­zol-4-yl)-1H-benzimidazole ligands, one Cl atom and one water mol­ecule in a distorted octa­hedral geometry. In the crystal, O—H⋯O, N—H⋯O and N—H⋯Cl hydrogen bon...

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Detalles Bibliográficos
Autores principales: Liang, Peng, Wu, Wei, Tian, Wei-Man, Yin, Xian-Hong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414103/
https://www.ncbi.nlm.nih.gov/pubmed/22904710
http://dx.doi.org/10.1107/S1600536812029728
Descripción
Sumario:In the title compound, [NiCl(C(10)H(7)N(3)S)(2)(H(2)O)]NO(3), the Ni(II) ion is coordinated by four N atoms from two chelating 2-(1,3-thia­zol-4-yl)-1H-benzimidazole ligands, one Cl atom and one water mol­ecule in a distorted octa­hedral geometry. In the crystal, O—H⋯O, N—H⋯O and N—H⋯Cl hydrogen bonds link the complex cations and nitrate anions into a three-dimensional network. π–π inter­actions between the thia­zole and imidazole rings and between the thia­zole and benzene rings are observed [centroid–centroid distances = 3.592 (3) and 3.735 (3) Å].

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