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Aquachloridobis[2-(1,3-thiazol-4-yl-κN)-1H-benzimidazole-κN (3)]nickel(II) nitrate
In the title compound, [NiCl(C(10)H(7)N(3)S)(2)(H(2)O)]NO(3), the Ni(II) ion is coordinated by four N atoms from two chelating 2-(1,3-thiazol-4-yl)-1H-benzimidazole ligands, one Cl atom and one water molecule in a distorted octahedral geometry. In the crystal, O—H⋯O, N—H⋯O and N—H⋯Cl hydrogen bon...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414103/ https://www.ncbi.nlm.nih.gov/pubmed/22904710 http://dx.doi.org/10.1107/S1600536812029728 |
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author | Liang, Peng Wu, Wei Tian, Wei-Man Yin, Xian-Hong |
author_facet | Liang, Peng Wu, Wei Tian, Wei-Man Yin, Xian-Hong |
author_sort | Liang, Peng |
collection | PubMed |
description | In the title compound, [NiCl(C(10)H(7)N(3)S)(2)(H(2)O)]NO(3), the Ni(II) ion is coordinated by four N atoms from two chelating 2-(1,3-thiazol-4-yl)-1H-benzimidazole ligands, one Cl atom and one water molecule in a distorted octahedral geometry. In the crystal, O—H⋯O, N—H⋯O and N—H⋯Cl hydrogen bonds link the complex cations and nitrate anions into a three-dimensional network. π–π interactions between the thiazole and imidazole rings and between the thiazole and benzene rings are observed [centroid–centroid distances = 3.592 (3) and 3.735 (3) Å]. |
format | Online Article Text |
id | pubmed-3414103 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-34141032012-08-17 Aquachloridobis[2-(1,3-thiazol-4-yl-κN)-1H-benzimidazole-κN (3)]nickel(II) nitrate Liang, Peng Wu, Wei Tian, Wei-Man Yin, Xian-Hong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [NiCl(C(10)H(7)N(3)S)(2)(H(2)O)]NO(3), the Ni(II) ion is coordinated by four N atoms from two chelating 2-(1,3-thiazol-4-yl)-1H-benzimidazole ligands, one Cl atom and one water molecule in a distorted octahedral geometry. In the crystal, O—H⋯O, N—H⋯O and N—H⋯Cl hydrogen bonds link the complex cations and nitrate anions into a three-dimensional network. π–π interactions between the thiazole and imidazole rings and between the thiazole and benzene rings are observed [centroid–centroid distances = 3.592 (3) and 3.735 (3) Å]. International Union of Crystallography 2012-07-04 /pmc/articles/PMC3414103/ /pubmed/22904710 http://dx.doi.org/10.1107/S1600536812029728 Text en © Liang et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Liang, Peng Wu, Wei Tian, Wei-Man Yin, Xian-Hong Aquachloridobis[2-(1,3-thiazol-4-yl-κN)-1H-benzimidazole-κN (3)]nickel(II) nitrate |
title | Aquachloridobis[2-(1,3-thiazol-4-yl-κN)-1H-benzimidazole-κN
(3)]nickel(II) nitrate |
title_full | Aquachloridobis[2-(1,3-thiazol-4-yl-κN)-1H-benzimidazole-κN
(3)]nickel(II) nitrate |
title_fullStr | Aquachloridobis[2-(1,3-thiazol-4-yl-κN)-1H-benzimidazole-κN
(3)]nickel(II) nitrate |
title_full_unstemmed | Aquachloridobis[2-(1,3-thiazol-4-yl-κN)-1H-benzimidazole-κN
(3)]nickel(II) nitrate |
title_short | Aquachloridobis[2-(1,3-thiazol-4-yl-κN)-1H-benzimidazole-κN
(3)]nickel(II) nitrate |
title_sort | aquachloridobis[2-(1,3-thiazol-4-yl-κn)-1h-benzimidazole-κn
(3)]nickel(ii) nitrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414103/ https://www.ncbi.nlm.nih.gov/pubmed/22904710 http://dx.doi.org/10.1107/S1600536812029728 |
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