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Aquachloridobis[2-(1,3-thia­zol-4-yl-κN)-1H-benzimidazole-κN (3)]nickel(II) nitrate

In the title compound, [NiCl(C(10)H(7)N(3)S)(2)(H(2)O)]NO(3), the Ni(II) ion is coordinated by four N atoms from two chelating 2-(1,3-thia­zol-4-yl)-1H-benzimidazole ligands, one Cl atom and one water mol­ecule in a distorted octa­hedral geometry. In the crystal, O—H⋯O, N—H⋯O and N—H⋯Cl hydrogen bon...

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Detalles Bibliográficos
Autores principales: Liang, Peng, Wu, Wei, Tian, Wei-Man, Yin, Xian-Hong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414103/
https://www.ncbi.nlm.nih.gov/pubmed/22904710
http://dx.doi.org/10.1107/S1600536812029728
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author Liang, Peng
Wu, Wei
Tian, Wei-Man
Yin, Xian-Hong
author_facet Liang, Peng
Wu, Wei
Tian, Wei-Man
Yin, Xian-Hong
author_sort Liang, Peng
collection PubMed
description In the title compound, [NiCl(C(10)H(7)N(3)S)(2)(H(2)O)]NO(3), the Ni(II) ion is coordinated by four N atoms from two chelating 2-(1,3-thia­zol-4-yl)-1H-benzimidazole ligands, one Cl atom and one water mol­ecule in a distorted octa­hedral geometry. In the crystal, O—H⋯O, N—H⋯O and N—H⋯Cl hydrogen bonds link the complex cations and nitrate anions into a three-dimensional network. π–π inter­actions between the thia­zole and imidazole rings and between the thia­zole and benzene rings are observed [centroid–centroid distances = 3.592 (3) and 3.735 (3) Å].
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spelling pubmed-34141032012-08-17 Aquachloridobis[2-(1,3-thia­zol-4-yl-κN)-1H-benzimidazole-κN (3)]nickel(II) nitrate Liang, Peng Wu, Wei Tian, Wei-Man Yin, Xian-Hong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [NiCl(C(10)H(7)N(3)S)(2)(H(2)O)]NO(3), the Ni(II) ion is coordinated by four N atoms from two chelating 2-(1,3-thia­zol-4-yl)-1H-benzimidazole ligands, one Cl atom and one water mol­ecule in a distorted octa­hedral geometry. In the crystal, O—H⋯O, N—H⋯O and N—H⋯Cl hydrogen bonds link the complex cations and nitrate anions into a three-dimensional network. π–π inter­actions between the thia­zole and imidazole rings and between the thia­zole and benzene rings are observed [centroid–centroid distances = 3.592 (3) and 3.735 (3) Å]. International Union of Crystallography 2012-07-04 /pmc/articles/PMC3414103/ /pubmed/22904710 http://dx.doi.org/10.1107/S1600536812029728 Text en © Liang et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Liang, Peng
Wu, Wei
Tian, Wei-Man
Yin, Xian-Hong
Aquachloridobis[2-(1,3-thia­zol-4-yl-κN)-1H-benzimidazole-κN (3)]nickel(II) nitrate
title Aquachloridobis[2-(1,3-thia­zol-4-yl-κN)-1H-benzimidazole-κN (3)]nickel(II) nitrate
title_full Aquachloridobis[2-(1,3-thia­zol-4-yl-κN)-1H-benzimidazole-κN (3)]nickel(II) nitrate
title_fullStr Aquachloridobis[2-(1,3-thia­zol-4-yl-κN)-1H-benzimidazole-κN (3)]nickel(II) nitrate
title_full_unstemmed Aquachloridobis[2-(1,3-thia­zol-4-yl-κN)-1H-benzimidazole-κN (3)]nickel(II) nitrate
title_short Aquachloridobis[2-(1,3-thia­zol-4-yl-κN)-1H-benzimidazole-κN (3)]nickel(II) nitrate
title_sort aquachloridobis[2-(1,3-thia­zol-4-yl-κn)-1h-benzimidazole-κn (3)]nickel(ii) nitrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414103/
https://www.ncbi.nlm.nih.gov/pubmed/22904710
http://dx.doi.org/10.1107/S1600536812029728
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