(Ethyl­enediamine-κ(2) N,N′)bis­(perchlorato-κO)bis­(pyridine-κN)copper(II)

In the title compound, [Cu(ClO(4))(2)(C(2)H(8)N(2))(C(5)H(5)N)(2)], the Cu(II) cation is located on a twofold rotation axis and is coordinated by four N and two O atoms in a tetragonally distorted octahedral geometry. The crystal packing can be described as ClO(4) tetra­hedra and CuN(4)O(2) octa­hed...

Descripción completa

Detalles Bibliográficos
Autores principales: Ourari, Ali, Bounab, Nawel, Bouacida, Sofiane, Aggoun, Djouhra
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414104/
https://www.ncbi.nlm.nih.gov/pubmed/22904711
http://dx.doi.org/10.1107/S1600536812029868
_version_ 1782240151909433344
author Ourari, Ali
Bounab, Nawel
Bouacida, Sofiane
Aggoun, Djouhra
author_facet Ourari, Ali
Bounab, Nawel
Bouacida, Sofiane
Aggoun, Djouhra
author_sort Ourari, Ali
collection PubMed
description In the title compound, [Cu(ClO(4))(2)(C(2)H(8)N(2))(C(5)H(5)N)(2)], the Cu(II) cation is located on a twofold rotation axis and is coordinated by four N and two O atoms in a tetragonally distorted octahedral geometry. The crystal packing can be described as ClO(4) tetra­hedra and CuN(4)O(2) octa­hedra alternating in a zigzag fashion along the c axis. The structure is stabilized by intermolecular N—H⋯O and C—H⋯O hydrogen bonds, as well as π–π interactions [centroid–centroid distance = 3.7179 (15) Å].
format Online
Article
Text
id pubmed-3414104
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-34141042012-08-17 (Ethyl­enediamine-κ(2) N,N′)bis­(perchlorato-κO)bis­(pyridine-κN)copper(II) Ourari, Ali Bounab, Nawel Bouacida, Sofiane Aggoun, Djouhra Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(ClO(4))(2)(C(2)H(8)N(2))(C(5)H(5)N)(2)], the Cu(II) cation is located on a twofold rotation axis and is coordinated by four N and two O atoms in a tetragonally distorted octahedral geometry. The crystal packing can be described as ClO(4) tetra­hedra and CuN(4)O(2) octa­hedra alternating in a zigzag fashion along the c axis. The structure is stabilized by intermolecular N—H⋯O and C—H⋯O hydrogen bonds, as well as π–π interactions [centroid–centroid distance = 3.7179 (15) Å]. International Union of Crystallography 2012-07-07 /pmc/articles/PMC3414104/ /pubmed/22904711 http://dx.doi.org/10.1107/S1600536812029868 Text en © Ourari et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ourari, Ali
Bounab, Nawel
Bouacida, Sofiane
Aggoun, Djouhra
(Ethyl­enediamine-κ(2) N,N′)bis­(perchlorato-κO)bis­(pyridine-κN)copper(II)
title (Ethyl­enediamine-κ(2) N,N′)bis­(perchlorato-κO)bis­(pyridine-κN)copper(II)
title_full (Ethyl­enediamine-κ(2) N,N′)bis­(perchlorato-κO)bis­(pyridine-κN)copper(II)
title_fullStr (Ethyl­enediamine-κ(2) N,N′)bis­(perchlorato-κO)bis­(pyridine-κN)copper(II)
title_full_unstemmed (Ethyl­enediamine-κ(2) N,N′)bis­(perchlorato-κO)bis­(pyridine-κN)copper(II)
title_short (Ethyl­enediamine-κ(2) N,N′)bis­(perchlorato-κO)bis­(pyridine-κN)copper(II)
title_sort (ethyl­enediamine-κ(2) n,n′)bis­(perchlorato-κo)bis­(pyridine-κn)copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414104/
https://www.ncbi.nlm.nih.gov/pubmed/22904711
http://dx.doi.org/10.1107/S1600536812029868
work_keys_str_mv AT ourariali ethylenediaminek2nnbisperchloratokobispyridinekncopperii
AT bounabnawel ethylenediaminek2nnbisperchloratokobispyridinekncopperii
AT bouacidasofiane ethylenediaminek2nnbisperchloratokobispyridinekncopperii
AT aggoundjouhra ethylenediaminek2nnbisperchloratokobispyridinekncopperii

Ejemplares similares